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  1. Article

    Open Access

    Application of GRAAL model to the resumption of International Simple Glass alteration

    The methodology developed for predicting nuclear waste behavior under disposal conditions combines experimental approaches and modeling. A waste glass canister placed in contact with water undergoes irreversib...

    Maxime Fournier, Pierre Frugier, Stéphane Gin in npj Materials Degradation (2018)

  2. Article

    Open Access

    Impact of alkali on the passivation of silicate glass

    Amorphous silica-rich surface layers, also called gels, can passivate silicate glass and minerals depending on environmental conditions. However, several uncertainties remain on the mechanisms controlling the ...

    Marie Collin, Maxime Fournier, Thibault Charpentier in npj Materials Degradation (2018)

  3. Article

    Open Access

    Chemical durability of peraluminous glasses for nuclear waste conditioning

    For the handling of high level nuclear waste (HLW), new glass formulations with a high waste capacity and an enhanced thermal stability, chemical durability, and processability are under consideration. This st...

    Victor Piovesan, Isabelle Bardez-Giboire, Maxime Fournier in npj Materials Degradation (2018)

  4. Article

    Open Access

    Structure of International Simple Glass and properties of passivating layer formed in circumneutral pH conditions

    Knowing the structure of a material is necessary to understand its evolution under various influences; here, the alteration by water of a reference glass of nuclear interest, called International Simple Glass ...

    Marie Collin, Maxime Fournier, Pierre Frugier in npj Materials Degradation (2018)

  5. Article

    Open Access

    Contribution of zeolite-seeded experiments to the understanding of resumption of glass alteration

    Understanding the origin and the consequences of glass alteration regimes is necessary for the prediction of nuclear glass durability. The so-called “stage 3” or “resumption of alteration regime” of glasses us...

    Maxime Fournier, Stéphane Gin, Pierre Frugier in npj Materials Degradation (2017)

  6. Article

    Open Access

    Various effects of magnetite on international simple glass (ISG) dissolution: implications for the long-term durability of nuclear glasses

    Understanding the effect of near-field materials, such as iron corrosion products, on the alteration of vitreous nuclear waste is essential for modeling long-term stability of these waste forms in a geological...

    Lindsey Neill, Stéphane Gin, Thomas Ducasse, Trilce De Echave in npj Materials Degradation (2017)