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Chapter
Organo-f-Element Thermochemistry. Implications for Reactivity and Bonding from Metal-Ligand Bonding Energetics
This article surveys the thermochemistry of organolanthanide and organoactinide complexes in several interrelated areas. For trivalent 4f and tetravalent 5f as well as tetravalent (d°) group 4 complexes, patte...
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Article
Synthesis, in vitro and in vivo characterization of 64Cu(I) complexes derived from hydrophilic tris(hydroxymethyl)phosphane and 1,3,5-triaza-7-phosphaadamantane ligands
Four novel 64Cu complexes ([64Cu(thp)4]+ (1), [64Cu(TPA)4]+ (2), [HC(CO2)(pzMe2)2 64Cu(thp)2] (3) and [HC(CO2)(tz)2 64Cu(thp)2] (4), [where thp is tris(hydroxymethy...
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Article
Cytotoxicity in human cancer cells and mitochondrial dysfunction induced by a series of new copper(I) complexes containing tris(2-cyanoethyl)phosphines
Over the last few years a lot of research has been done to develop novel metal-based anti-cancer drugs, with the aim of improving clinical effectiveness, reducing general toxicity, and broadening the spectrum ...
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Article
Open AccessTherapeutic potential of the phosphino Cu(I) complex (HydroCuP) in the treatment of solid tumors
[Cu(thp)4][PF6] (HydroCuP) is a phosphino copper(I) complex highly soluble and stable in physiological media that has been developed as a possible viable alternative to platinum-based drugs for anticancer therapy...