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Article
Zirconium-containing metal organic frameworks as solid acid catalysts for the N-formylation of aniline with formic acid
Porous Zr-based metal–organic frameworks (MOF-808 and MOF-808/H2SO4, UiO-66 and UiO-66-SO3H) were used as solid acid catalysts for N-formylation of aniline with formic acid (aniline/formic acid 1/2 mol/mol, 35 °C...
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Article
Synthesis of 1,5-benzodiazepine from 1,2-phenylenediamine and acetone in the presence of catalytic systems based on montmorillonite: effect of the surface acidity
The effect of the surface acidity of catalytic systems based on montmorillonite (Mt) on the formation of 1,5-benzodiazepine from 1,2-phenylenediamine and acetone was investigated. Two strategies were used for ...
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Article
Iron-containing materials as catalysts for the synthesis of 1,5-benzodiazepine from 1,2-phenylenediamine and acetone
The cyclocondensation of 1,2-phenylenediamine (I) with acetone was investigated in the presence of Fe-containing microporous nickel phosphate molecular sieves (Fe-VSB-5) and Fe-containing mesoporous mesophase ...
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Article
Laser flash photolysis study of photocatalytic properties of pillared interlayered clays and Fe,Al-silica mesoporous catalysts
Laser flash photolysis was applied to determine the primary photochemical processes over iron-containing clay (montmorillonite KSF), pillared interlayered clays (PILCs) and mesoporous mesophase iron silicate m...