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Tens of thousands of atoms replaced by one
Many catalysts comprise metal nanoparticles on solid supports. The discovery that single atoms of palladium anchored to a solid support also exhibit high catalytic activity might help to conserve the supply of...
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The birth of X-ray crystallography
A century ago this week, physicist Lawrence Bragg announced an equation that revolutionized fields from mineralogy to biology, writes John Meurig Thomas.
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The many faces of carbon
An enticing new book ties together the vital roles this element has in life, the Universe and climate change, explains John Meurig Thomas.
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Scientist, social reformer, soldier, spy
From a Massachusetts farm to the court of England's George III, and beyond.
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Energetic Victorians
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Molecular-sieve catalysts for the selective oxidation of linear alkanes by molecular oxygen
Terminally oxidized hydrocarbons are of considerable interest as potential feedstocks for the chemical and pharmaceutical industry, but the selective oxidation of only the terminal methyl groups in alkanes rem...
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Faraway Faraday
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A conquering man of genius
The Correspondence of Michael Faraday Vol. 1,1811-31 (1991), pp. 673, £65; vol. 2,1832-40(1993), pp. 807, £65; vol. 3,1841-48 (1996), pp. 835, £65
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Geoffrey Wilkinson (1921–96)
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De novo design of structure-directing agents for the synthesis of microporous solids
THE synthesis of microporous materials such as aluminosilicates and aluminophosphates, which are widely exploited as solid acid catalysts, ion exchangers and in gas separation, is facilitated by the use of st...
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Heterogeneous catalysts obtained by grafting metallocene complexes onto mesoporous silica
THE synthesis of mesoporous siliceous solids with large-diameter channel apertures (25–100 Å) has greatly expanded the capabilities of heterogeneous catalysis1–7. The large apertures in such mesoporous silicas ca...
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The chemistry of crystalline sponges
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Architecture of the invisible
From the structure of sodium chloride to that of a human rhinovirus complexed with its receptor — X-ray crystal analysis has taken an extraordinarily fruitful path since its inception 80 years ago.
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Tracing the conversion of aurichalcite to a copper catalyst by combined X-ray absorption and diffraction
EVER since X-ray sources first became available, the merit of deploying diffraction and absorption spectroscopic studies simultaneously has been acknowledged1. Information on oxidation states and local (~6-Å radi...
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Femtosecond diffraction