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Chapter
Reaction of Alkynols with Alkynylalkoxycarbene Metal (Cr,W) Complexes
The reaction of alkynols with the title complexes follows different pathways depending on the type of acetylene (mono or disubstituted) and the mutual distance between functionalities giving, as a consequence,...
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Chapter
Alkynylcarbene Complexes of Transition Metals as Suitable Substrates for Stereoselective Cycloadditions
Strong electronic effects of the carbene-metal unit on the adjacent functionalities in alkynylcarbene metal (Cr,W) complexes may be regarded as the main cause for easy and stereocontrolled cycloadditions with ...