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    Chapter

    Reaction of Alkynols with Alkynylalkoxycarbene Metal (Cr,W) Complexes

    The reaction of alkynols with the title complexes follows different pathways depending on the type of acetylene (mono or disubstituted) and the mutual distance between functionalities giving, as a consequence,...

    J. M. Viñas, J. M. Moreto, S. Ricart in Transition Metal Carbyne Complexes (1993)

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    Chapter

    Alkynylcarbene Complexes of Transition Metals as Suitable Substrates for Stereoselective Cycloadditions

    Strong electronic effects of the carbene-metal unit on the adjacent functionalities in alkynylcarbene metal (Cr,W) complexes may be regarded as the main cause for easy and stereocontrolled cycloadditions with ...

    L. Jordi, A. Llebaria, S. Ricart, J. M. Viñas in Transition Metal Carbyne Complexes (1993)