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Article
Removal of rare earth elements and thorium from LiCl–KCl molten salt by phosphate precipitation method
The removal of rare earth fission products and thorium from LiCl–KCl system is of great significance to purification and recovery LiCl–KCl during pyroprocessing flow. The removal efficiency of rare earth eleme...
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Article
Removal of rare earth fission products from LiCl–KCl molten salt by sulfide precipitation
The precipitation reaction of rare earth was investigated by potassium sulfide (K2S), or sodium sulfide hydrate (Na2S·xH2O) in LiCl–KCl melts. The characteristics of precipitates were determined and the removal r...
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Article
Effects of bismuth do** on the physical and electrochemical properties of Na3V2-xBix (PO4)3/C (0 ≤ x ≤ 0.07) composite cathode materials
Na3V2-xBix(PO4)3/C (0 ≤ x ≤ 0.07) samples were prepared by a facile sol-gel method. Dependence of their physical and electrochemical properties on the amount of Bi3+ do** are investigated by X-ray diffraction (...
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Article
The distillation behavior of fluorides in LiCl–KCl molten salt
The distillation behaviors of some fission product fluorides in LiCl–KCl system were investigated. For rare earth element, the corresponding decontamination factors (DFs) of Ce in 5 wt% CeF3–LiCl–KCl salts were o...
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Article
Trace impurities analysis in UF4 via standard addition and 103Rh internal standardization techniques combined with ICP-MS
In order to determine trace impurities in the nuclear grade UF4, an analysis method based on the standard addition and 103Rh internal standardization techniques combined with ICP-MS has been established. The exam...
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Article
The evaporation behaviors of rare-earth-doped FLiNaK melts during low-pressure distillation
Low pressure distillation of FLiNaK containing rare earth fluorides was carried out to investigate evaporation behaviors of FLiNaK as well as decontamination of rare earth fluorides. Evaporation rate of NdF3–FLiN...
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Article
Pulse radiolysis investigation of · OH and · H radicals initiated degradation reaction of sulfonated aromatics as model compounds for proton exchange membrane
In order to predict · OH and · H radicals initiated degradation of proton exchange membrane (PEM) based on polymers obtained by radiation-indu...
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Article
Structural analysis of [Bmim]2CuCl4 ionic liquids in the presence of water and ethanol by XAFS technique
The structure of [Bmim]2CuCl4 ionic liquids (Bmim: 1-butyl-3-methylimidazolium) with different ratios of H2O and C2H5OH was investigated using X-ray absorption fine structure (XAFS) technique. In this study, XAFS...
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Article
Pulse radiolysis study on gatifloxacin — A fluoroquinolone antibiotic
The reactions between gatifloxacin (GFX) and various one-electron oxidants, such as ·OH, N3 ·, Br2 ·−, and SO4 ·−, have been studied by pulse radiolysis techniques....
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Article
Pulse radiolysis studies of intermolecular charge transfers involving tryptophan and three-electron-bonded intermediates derived from methionine
The oxidation processes of the radiation-generated, three-electron-bonded intermediates AcMet2 [S∴S]+ and AcMet [S∴Br] were investigated by pulse radiolysis via their reactions with tryptophan (TrpH). These inter...
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Article
Laser photolysis studies of quaternary ammonium ionic liquids aqueous solution
The reactions between quaternary ammonium ionic liquids ([Me3NC2H4OH]+[Zn2Cl5]−, abbrev. Ch-Zn2Cl5) and one-electron oxidant (SO 4 •− ), have been studied by na...