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Article
Surface modification of colloidal silica particles
Colloidal silica particles in organic solvents were grafted, using several reagents, in order to make them hydrophobic. The hydrophobicity of the beads could be easily varied. Quasielastic light scattering an...
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Article
Highly hydrophobically modified polyelectrolytes stabilizing macroemulsions: relationship between copolymer structure and emulsion type
The types of emulsions, oil (n-dodecane) in water (O/W) or water in oil (W/O), stabilized with highly hydrophobically grafted linear poly(sodium acrylate)s, were investigated as a function of polymer chemical ar...
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Article
Highly hydrophobically modified polyelectrolytes: Field variables to control emulsion type
Highly hydrophobically modified (with n-dodecylamide chain) linear poly(acrylic acid)s (HHMPAAH) and poly(sodium acrylate)s (HHMPAANa) with various degrees of grafting (τ) were synthesized and used as emulsifier...
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Article
Coupling between polymer adsorption and colloidal particle aggregation
Studies of the adsorption of high molecular weight polymers on colloidal latex and silica particles and their subsequent flocculation were carried out. Neutral polyethylene oxide samples with both a narrow and...
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Article
Rheological behavior of moderately concentrated silica suspensions in the presence of adsorbed poly(ethylene oxide)
Adsorption and flocculation properties have been investigated for a well-characterized aqueous system of precipitated nanometric silicabeads in the presence of a high molecular-weight poly(ethylene oxide). Par...
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Article
Reversible flocculation of silica suspensions by water-soluble polymers
The possibility to concentrate, then redisperse colloidal suspensions is not only of great theoretical interest, but is also relevant to the industrial process of solid-liquid separation, which must often be f...
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Article
Short range order of silica particles bound through adsorbed polymer layers
Small angle neutron scattering was used to examine the organization of silica spheres which had been flocculated by various cationic copolymers. When the adsorbed polymers bound the spheres without compensatin...