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Article
Spherical TiO2/Cr2O3 Composites Synthesized with the Use of Ion-Exchange Resins as a Template
Two samples of TiO2/Cr2O3 composites are synthesized in the form of spherical grains via the stagewise thermal treatment of ion-exchange resins preliminarily saturated with chromium Cr3+ cations and dichromate ...
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Article
Effect of the Cr/Fe ratio on the structure of Fe-Cr-Cu-containing oxide catalysts
The morphology and structural and electronic states of nanodispersed copper ferrite-chromites of with different Cr/Fe ratios calcined at 900°C in an atmosphere of air were studied using a set of physical metho...
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Article
Mechanism and kinetics of hydrogen oxidation on silver
The kinetic study of the stationary oxidation of hydrogen on silver was carried out. The dependences of the reaction rate on the ratios of hydrogen and oxygen in the reaction mixture under a constant total pre...
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Article
Interaction of hydrogen and water with oxygen adsorbed on silver
The identity of surface silver hydroxides produced by hydrogenation or hydration of surface silver oxide was demonstrated. A two-route mechanism of hydrogen interaction with oxygen adsorbed on silver was sugge...
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Article
The effect of the precursor structure on the catalytic properties of the nickel—chromium catalysts of hydrogenation reactions
The influence of the Ni2+/Cr3+ ratio in the precursor compound on the formation of the catalyst structure and its transformation upon the thermal treatment and reductive activation in hydrogen was studied. The pr...
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Article
Synthesis of an efficient catalyst based on nickel and chromium oxides for hydrogenation reactions
The dissolution of nickel metal in nitric acid in the presence of the dichromate anion as the oxidizer is reported. The formation of Ni(II) and Cr(III) nitrates takes place in two steps with the intermediate f...