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    Functional substitution of coordination polyhedron in crystal structure of silicates

    On the bases of the study of comparative crystal chemistry of silicates it has been concluded that the octahedra and square pyramids of Ti-0 and Zr-0 play functional role of tetrahedra of Si-0 in the construct...

    Danian Ye, D. Pushcharovsky, Nicheng Shi… in Science in China Series D: Earth Sciences (2002)