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  1. No Access

    Article

    Chlorination of Sulfonium Derivatives of closo-Decaborate Anion with Carboxyl-Containing Substituents

    The reaction of sulfonium closo-decaborate derivatives containing carboxyl groups with sulfuryl chloride SO2Cl2 as a halogenating agent was studied. The reaction gave fully halogenated derivatives of the closo-de...

    A. V. Golubev, A. S. Kubasov, A. Yu. Bykov… in Doklady Chemistry (2021)

  2. No Access

    Article

    Methods of Creating closo-Decaborate Anion Derivatives with Bridging and Terminal Exopolyhedral Cyclic Substituents of Sulfonium Type

    New methods of creation of cyclic bridging and terminal exopolyhedral sulfur-containing substituents in the closo-decaborate anion have been suggested. It has been shown that the reaction of [B10H9SH]2– with 1,2-...

    A. S. Kubasov, E. Yu. Matveev, E. S. Turyshev, I. N. Polyakova… in Doklady Chemistry (2018)

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    Article

    Nickel(II) and Iron(II) coordination compounds with octahydrotriborate(1–) anion [ML3]{B3H8}2 (M = Fe2+, Ni2+; L = bipy, phen)

    Methods of synthesis have been developed for new types of promising precursors of metal borides, coordination compounds [ML3]B{3H8{2 (M = Fe2+, Ni2+; L = bipy, phen), using modified procedures of synthesis of oct...

    N. A. Selivanov, A. Yu. Bykov, M. S. Grigor’ev, K. Yu. Zhizhin… in Doklady Chemistry (2016)

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    Article

    Complexes of gold clusters with the closo-borate anions B10H 10 2− and B12H 12 2−

    E. A. Malinina, V. V. Drozdova, A. Yu. Bykov, O. N. Belousova… in Doklady Chemistry (2007)