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Article
EIS analysis of electrode kinetics for La2NiO4 + δ cathode in contact with Ce0.8Sm0.2O1.9 electrolyte: from DRT analysis to physical model of the electrochemical process
The oxygen reduction kinetics on an La2NiO4 + δ electrode for electrodes of different thicknesses was investigated by means of electrochemical impedance spectroscopy. Dependences of the polarisation resistance in...
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Article
Oxygen isotope exchange in praseodymium nickelate
Oxygen surface exchange kinetics and diffusion were studied in Pr2NiO4 + δ (PNO) by the isotope exchange method with gas phase equilibration in the temperature range of 600–800 °C and oxygen pressure range of 0.3...
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Article
Single SOFC with Supporting Ni-YSZ Anode, Bilayer YSZ/GDC Film Electrolyte, and La2NiO4 + δ Cathode
Characteristics of fuel cells with supporting Ni-YSZ anode, bilayer YSZ/GDC electrolyte with the thickness of 10 μm, and La2NiO4 + δ cathode are studied. It is shown that when humid (3% water) hydrogen is supplie...
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Article
Oxygen isotope exchange between the gas-phase and the electrochemical cell O2, Pt | YSZ | Pt, O2 under conditions of applied potential difference
The kinetics of oxygen isotope exchange between gas-phase oxygen and the electrochemical cell O2, Pt | ZrO2 + 10 mol % Y2O3 (YSZ) | Pt, O2 with applied potential difference (ΔU = ±1.2 V) is studied in the tempera...
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Article
Phase equilibria, water dissolution, and peculiarities of charge transfer in Ca-doped La2Zr2O7–α
A series of oxides La2 - x Ca x Zr2O7–α (x = 0.00, 0.05, 0.10, 0.15, 0.20) is synthesized. It is found that in samples with the calcium content x ...
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Article
Oxygen isotope exchange in the LSM-YSZ composite under the conditions of long-term tests
The stability of the properties of the composite 40 vol % La0.6Sr0.4MnO3 − δ-60 vol % Zr0.83Y0.17O1.92 (LSM-YSZ) held for 1000 h at a temperature of 800°C and an oxygen pressure of 1.01 kPa and changes in its mic...