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  1. No Access

    Article

    Replacement of Fe atoms by Ru in a carbidocarbonyl cluster [Fe6C(CO)16]2−. Structures of reaction products

    The reaction of the carbidocarbonyl cluster [Fe6C(CO)16]2− with ruthenium(IV) hydroxochloride Ru(OH)Cl3 was studied. At 90–100 °C, the reaction gave products of replacement of Fe atoms by Ru in the [Fe6C(CO)16]2−

    S. P. Gubin, L. G. Kuz'mina, A. V. Churakov, J. A. K. Howard… in Russian Chemical Bulletin (2005)

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    Article

    Analysis of chiroptical properties of π-allyl complex [Pd(β-pinenyl)Cl]2

    Electronic absorption and circular dichroism spectra of the optically active [Pd(β-pincnyl)Cl]2 complex (1) have been studied. The assignment of the bands in the circular dichroism spectrum in the d—d-transition ...

    A. P. Klyagina, T. V. Misailova, I. F. Golovaneva, S. P. Gubin in Russian Chemical Bulletin (1996)

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    Article

    Correlation between stereochemistry and sign of cotton effects for degenerate transitions in spectra of binuclear clusters of molybdenum(II)

    A correlation between the stereochemistry and sign of the Cotton effect for π → δ* transition in the spectra of dimolybdenum tetracarboxylates and related compounds has been accomplished by constructing, within t...

    A. P. Klyagina, I. F. Golovaneva… in Bulletin of the Academy of Sciences of the… (1990)

  4. No Access

    Article

    Correlation between the stereochemistry and optical activity of chiral dimolybdenum tetracarboxylates and related compounds

    Sector rules for chiral dimolybdenum tetracarboxylates and related compounds were derived using the “one-electron model” of optical activity. The correlation between the sign of the Cotton effect (CE) of the δ→δ*

    A. P. Klyagina, I. F. Golovaneva… in Bulletin of the Academy of Sciences of the… (1990)

  5. No Access

    Article

    Electronic structure of a ruthenium dimer

    The electronic structure of a ruthenium dimer is calculated by SW-Xα. The configuration lσg2πu 4δg 4δu 42σg2, corresponding to a quadruple bond and an equilibrium distance of 1.94 A are found. Ionization potentia...

    V. D. Lutatskaya, A. P. Klyagina… in Bulletin of the Academy of Sciences of the… (1989)

  6. No Access

    Article

    Electron structure of the V2 molecule derived from DV-Xα data

    The electron structure of the V2 molecule has been calculated by means of the DV-Xα method. The configuration 3πu 46σg 27σg 2(lδg↑)2 has been obtained for the ground state, which corresponds to a quintuple bond, ...

    V. D. Fursova, A. P. Klyagina, A. A. Levin… in Bulletin of the Academy of Sciences of the… (1985)