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Article
Copper-catalyzed enantioselective desymmetrizing C(sp2)–H functionalization of azide-ynamides via α-imino copper carbenes
α-Imino metal carbenes are versatile intermediates in organic synthesis, and have broad applications in the assembly of divergent N-heterocycles. However, the catalytic enantioselective desymmetrization based on
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Article
MOF-Derived Bimetal-Embedded Carbon with Etched Morphologies as an Efficient Activator of Peroxymonosulfate for Eliminate Emerging Contaminants
As bis(4-hydroxyphenyl)methanone (BHP) is one of the most common UV light stabilizers (UVLS), but exhibits endocrine disrupting toxicity, this study aims to develop useful sulfate radical-based techniques to e...
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Article
Mechanical behavior and property evaluations of electromagnetic shielding/far infrared functional composite boards made of nano carbon-stainless steel knitted fabrics and far infrared polypropylene
This study introduces functional composite boards, combining nano carbon yarns, stainless steels, and far-infrared (FIR) polypropylene (PP). Stainless steel filaments are wrapped in nano carbon fibers to form ...
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Article
Random and site-specific radiolabeling of [89Zr]Zr-DFO-anti-PD-L1-mAb iPET tracer
Zirconium-89 radiolabeled immuno-positron emission tomography (89Zr-iPET) has become a critical tool for patient stratification before and after immunotherapies for therapeutic evaluation. In this study, random a...
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Article
Design of Tough, yet Strong, Heat-resistant PLA/PBAT Blends with Reconfigurable Shape Memory Behavior by Engineering Exchangeable Covalent Crosslinks
Polylactide (PLA) has often been blended with biodegradable poly(butylene adipate-co-terephthalate) (PBAT) to improve it toughness. However, the strength and heat resistance of PLA are always sacrificed. Herein, ...
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Article
Spiro-salen catalysts enable the chemical synthesis of stereoregular polyhydroxyalkanoates
Although bacterial stereoregular polyhydroxyalkanoates have attracted broad interest as sustainable materials, it remains a long-standing challenge to chemically synthesize stereoregular polyhydroxyalkanoates ...
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Article
Rapid detection of EGFR mutation in CTCs based on a double spiral microfluidic chip and the real-time RPA method
Circulating tumor cells (CTCs) are cells shed from primary or metastatic tumors and spread into the peripheral bloodstream. Mutation detection in CTCs can reveal vital genetic information about the tumors and ...
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Article
Investigation of the optimal production conditions for egg white hydrolysates and physicochemical characteristics
This study aimed to investigate the potential of egg white protein hydrolysate (EWH) as a functional food by identifying the optimum production conditions for EWH with response surface methodology (the results...
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Article
Porous organic polymers: a progress report in China
Porous organic polymers (POPs) are porous materials composed of light elements such as C, H, N, and O. The benign characters, including large surface area, good physical and chemical stability, well-defined ch...
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Article
Open AccessEngineering a norcoclaurine synthase for one-step synthesis of (S)-1-aryl-tetrahydroisoquinolines
Tetrahydroisoquinoline alkaloids (THIQAs) are ubiquitous compounds with important pharmaceutical and biological activity. Their key N-heterocyclic structural motifs are synthesised via Pictet–Spengler (P–S) react...
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Article
Manipulating and Revealing the Roles of La and Zr Dopants into ZnTiO3 Perovskite Toward Heterogeneous Photocatalytic Degradation of Tetracycline Under Visible Light Irradiation
Various ZnTiO3 perovskites replacing A and B sites by La, Zr dopants were successfully synthesized via the ultrasonic-assisted sol–gel method. Different calcination temperatures, La–Zr dopants were examined, foll...
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Article
Open AccessDesign of an open-shell nitrogen-centered diradicaloid with tunable stimuli-responsive electronic properties
Organic diradicaloids usually display an open-shell singlet ground state with significant singlet diradical character (y0) which endow them with intriguing physiochemical properties and wide applications. In this...
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Article
Open AccessRegiospecific C–H amination of (−)-limonene into (−)-perillamine by multi-enzymatic cascade reactions
(−)-Limonene, one of cyclic monoterpenes, is an important renewable compound used widely as a key building block for the synthesis of new biologically active molecules and fine chemicals. (−)-Perillamine, as d...
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Article
Synthesis, Preparation and Evaluation of Doxorubicin-Loaded Chitosan Oligosaccharide/Indomethacin Nanoparticles
Doxorubicin(DOX)-loaded chitosan oligosaccharide(CSO)/indomethacin(Indo) nanoparticles(NPs) was developed as a uniform particle size, high drug loaded capacity, good biostability and biocompatibility drug deli...
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Article
Selective adsorption and separation of Cu(II) from Zn solution by CU resin
The aim of present study was to determine the efficiency of CU selective resin for separation of radionuclides Cu from large excess of Zn. Adsorption behaviors towards Cu2+ ions was investigated as function of so...
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Article
Open AccessIntegrin α2β1-targeting ferritin nanocarrier traverses the blood–brain barrier for effective glioma chemotherapy
Ferritin, the natural iron storage protein complex, self-assembles into a uniform cage-like structure. Human H-ferritin (HFn) has been shown to transverse the blood–brain barrier (BBB) by binding to transferri...
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Article
A statistical evaluation of the liquid effluent release from NPP based on analytical methods with low detection limits
Eight liquid effluent samples from nuclear power plants (NPP) were analyzed for 63Ni, 131I, and gamma radionuclides using methods with low detection limits. The sum of the radionuclides activity concentrations of...
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Article
Open AccessSuperparamagnetic iron oxide nanoparticles conjugated with Aβ oligomer-specific scFv antibody and class A scavenger receptor activator show therapeutic potentials for Alzheimer’s Disease
Alzheimer’s disease (AD) is a progressive neurodegenerative disorder. No disease-modifying strategy to prevent or delay AD progression currently exists. Aβ oligomers (AβOs), rather than monomers or fibrils, ar...
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Article
Preface to the Special Issue on “Heterogeneous Photocatalysts: From Fundamentals to Innovative Applications”
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Article
Solvothermal Synthesis of Mesoporous TiO2 Using Sodium Dodecyl Sulfate for Photocatalytic Degradation of Methylene Blue
Mesoporous titanium dioxide (TiO2) photocatalysts were synthesized via a solvothermal method using sodium dodecyl sulfate (SDS) as templates. The effect of the SDS concentration and solution pH value on the resul...