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Article
Open AccessTuning the melting point and phase stability of rare-earth oxides to facilitate their crystal growth from the melt
The challenge of growing rare-earth (RE) sesquioxide crystals can be overcome by tailoring their structural stability and melting point via composition engineering. This work contributes to the advancement of ...
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Article
High Conducting Heterovalent Substituted NASICON-like Phases in ScPO4-Na3PO4Quasibinary System
Phase equilibria in quasibinary system ScPO4-Na3PO4 and formation of heterovalent Zr-substituted solid solutions (up to 10 mol%) for Sc3+ in Na3Sc2(PO4)3 complex phosphate were studied by ceramic technique at 105...
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Article
NASICON-like phases in ScPO4-Na3PO4-Li3PO4 quasiternary system
Phase formation in ternary system of complex Sc, Na and Li phosphates was studied at 950°C and synthesis of new phases of definite composition was carried out. Obtained samples were investigated with X-ray pow...