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Article
Industrial applications of the aggregation of block copolymers in supercritical CO2: a SANS study
Industrial applications of supercritical carbon dioxide (scCO2) rely upon the rather selective and easily adjustable solvent ability of CO2. CO2 near the critical point is a poor solvent for high molecular weight...
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Article
Extraction of a hydrophilic compound from water into liquid CO2 using dendritic surfactants
Dendrimers are well defined, highly branched polymers1,2,3,4,5 that adopt a roughly spherical, globular shape in solution. Their cores are relatively loosely packed and can trap guest molecules5,6,7, and by appro...
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Article
Evaluation of matrix-assisted laser desorption ionization mass spectrometry for polymer characterization
A protocol for the preparation of polymeric samples for time-of-flight matrix-assisted laser desorption ionization mass spectrometry (TOF-MALDI-MS) analysis was developed. Dithranol was identified as a good ma...
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Article
Structural Characterization of a Polymer Substituted Fullerene (Flagellene) by Small Angle Neutron Scattering
Small-angle neutron scattering (SANS) can structurally characterize fullerenes’ in solvents with strong SANS contrast (e.g. CS2). Deuterated solvents (e.g. toluene-d8) have a high scattering length density (SLD),...