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Article
INVESTIGATION ON THE FLUORESCENT PROPERTY AND THE HIRSHFELD SURFACE ANALYSIS OF A NOVEL HETEROBIMETALLIC Cd(II)—Na(I) PYRIDINE-TERMINAL SALAMO-TYPE COORDINATION POLYMER
A novel heterometallic Cd(II)–Na(I) coordination polymer (Cd(II)–Na(I) CP), [{Cd(H2L)(OAc)(μ2-OAc)Na(OAc)(MeOH)(EtOH)}2]n is self-assembled via a reaction between Cd(OAc)2·H2O, NaN(CN)2, and a salamo-type ligand ...
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Article
A Triphenylamine Derivative-based Fluorescent Probe with Good Water Solubility for Targeting Aβ Plaques in Alzheimer’s Disease
A triamine aryl pyrazole-based NIR fluorescent probe with good water solubility has been developed for detecting and imaging Aβ aggregates in Alzheimer’s disease. In vitro studies have demonstrated that the probe...
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Article
Coordination Properties and Fluorescence of a Structurally Novel Zn(II) Pyridine-Terminal Salamo-Type Coordination Polymer
A novel two-dimensional Zn(II) coordination polymer [Zn(II) CP], [{Zn(L)Zn(OAc–)(µ-OAc–)}4]n· 2nCH3CH2OH has been self-assembled from Zn(OAc)2·2H2O. It contains pyridine-terminal salamo-type ligan...
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Article
INSIGHT INTO FLUORESCENT PROPERTIES, DFT AND HIRSHFELD ANALYSES OF A NEWLY SYNTHESIZED AND STRUCTURALLY NOVEL TRINUCLEAR COPPER(II) SALAMO-BASED COMPLEX INVOLVING PHENOXO-O BRIDGED COORDINATION
A novel trinuclear Cu(II) (Cu2+:(L)3− = 3:2) complex derived from a newly designed pentadentate salamo-based ligand (H3L), namely [Cu3(L)2(CH3OH)2]·CH3COCH3, is synthesized. This structure is different from the s...
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Article
Preparation, Two-Photon Absorption, and Bioimaging Application of a Curcumin-Based Copper(II) Complex
A new multi-branched model Cu(II) complex based on curcumin, namely CuL2(I) (НL = (1E,4Z,6E)-1,7-bis(4-(4-bromobutoxy)-3-methoxyphenyl)-5-hydroxyhepta-1,4,6-trien-3-one, C29H34O6Br2), was prepared and its two-pho...
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Article
AN NOVEL ANTIBACTERIAL ACTIVE [CuII–GdIII] COMPLEX CONSTRUCTED FROM AN ASYMMETRIC SALAMO-BASED LIGAND: SYNTHESIS AND STRUCTURAL CHARACTERIZATION
In the present study, we describe a reaction of Cu(OAc)2·H2O and Gd(NO3)3·6H2O with equimolar amounts of the asymmetric salamo-type ligand 6-methoxy-6′-ethoxy-2,2′-[ethylenedioxybis(azinomethyl)]diphenol (H2L) ge...
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Article
A Perspective on Molecular Structure and Experimental-Computational Characterization of a Novel Cd(II) Pyridine-Terminal Salamo-like Coordination Polymer
A structurally novel Cd(II) coordination polymer (CP), [Cd(H2L)2(NCS)2]n, has been self-assembled from a newly designed salamo-like ligand H2L bearing double terminal pyridine groups, Cd(II) and KSCN. The Cd(II) ...
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Article
Synthesis, Two-Photon Absorption, and Cellular Imaging of Two Curcumin Derivatives
Two curcumin derivatives, 1,7-bis(4-bromoethyloxy-3-methoxyphenyl)-1,6-heptadiene-3,5-dione (1) and 1,7-bis(4-bromobutyloxy-3-methoxyphenyl)-1,6-heptadiene-3,5-dione (2), have been conveniently synthesized and th...
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Article
DNA binding, DNA cleavage, and cellular imaging of a copper(II) complex based on curcumin
Binding property between CT-DNA and a Cu(II) complex, namely CuL2, where HL = 1,7-bis(4-butoxy-3-methoxyphenyl)hepta-1,6-diene-3,5-dione, was determined by UV–Vis absorption, fluorescence spectroscopy, and viscos...
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Article
Three new Co(II)/Ni(II) cordination polymers based on 3,3-biphenyl dicarboxylic acid and N-donor Co-ligands: Synthesis, crystal structures and magnetic properties
Three new Co(II)/Ni(II) cordination polymers [Co(Bpdc)(Bipy)] n (I) and [Co2(Bpdc)2(Dps)2] n (II) and [Ni(Bpdc](Dps)] n ...
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Article
Hydrothermal synthesis, crystal structure, and luminescent property of a cobalt(II) complex based on carbazole derivative
A new cobalt(II) mononuclear complex, formulated as [Co(HL)2(H2O)2] (I), has been successfully synthesized by self-assembly of cobalt nitrate with 9-ethylcarbazole-3,6-dicarboxylic acid (H2L) under hydrothermal c...
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Article
Research of specific heat capacities of three large seaweed biomass
Based on the differential scanning calorimeter (DSC) in traditional solution method, the modification considering the mass loss was put into the measurement of specific heat capacities, which made the measured...