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Article
Synthesis, structure and the e.s.r. spectrum of the mixed-valence molybdovandate Na2(NH4)4[(VIVVV8Mo)O28] · 10H2O
The mixed-valence molybdovanadate compound Na2(NH4)4[VIVVV 8Mo)O28] · 10H2O [Vanadata(6-)tetradeca-μ-oxotetra-μ3-oxodi-μ6-oxoheptaoxo(oxomolybdate) nonatetrammonium disodium, decahydrate] has been synthesized fro...
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Article
Synthesis, crystal structure and magnetic properties of A[Ni(mnt)2] complexes [A = 1-(4-nitrobenzyl)quinolinium or 1-benzylpyridinium; mnt2− = maleonitriledithiolate]
Two new ion-pair complexes A[Ni(mnt)2], [A = 1-(4-nitrobenzyl)quinolinium (1), and 1-benzylpyridinium (2)] have been prepared and characterized. The crystal structure of (1) has been determined by X-ray diffracti...
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Article
Synthesis, crystal structure, and properties of [Cu(LH)]2[M(mnt)2] [M = Ni or Cu; H2L = 3,3′-(1,3-propanediyldinitrilo)-bis(2-butanone oxime); mnt2− = maleonitriledithiolate] complexes containing bridging cyano groups
Interesting complexes containing a mnt2− bridge, based on the reaction of [M(mnt)2]2− [M = Ni or Cu] with [Cu(LH)]+, have been prepared and characterized by e.s.m.s., i.r and u.v–vis. spectroscopic techniques and...
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Article
Racemic titanium(IV) complexes of salicylideneamino acids
New racemic complexes of titanium with Schiff bases derived from condensation of salicylaldehyde with dl-alanine (H2Sal-dl-Ala) and dl-valine (H2Sal-dl-Val) have been prepared. The crystal structure of [(Sal-dl-V...