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Stark effect in odd-parity J = 1 levels of neutral barium
Stark splitting of the barium 6 snp 1 P 1 states with principal quantum numbers ranging from 8 to 15 and of the 5 d 7 p 1 P 1 perturber level was...
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Accurate ab initio determination of the van der Waals interaction in the X 2Σ+ ground state of LiHe
Accurate quantum-chemical ab initio calculations have been performed at the SCF and CEPA (coupled electron pair approximation) levels for the van der...
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Ground state correlations of jellium metal clusters in local spin-density approximation
The role of S = 1 excitations on the ground state of jellium clusters is analyzed within the randomphase approximation (RPA). The importance of the...
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Valence force field model for graphene and fullerenes
We present two Valence Force Field models for sp 2 bonded carbon sheets with three and five parameters adjusted to the phonon frequencies of...
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Pauling’s resonating valence bond theory of metals: some studies on lithium clusters
We report for the first time fully ab initio valence bond (VB) calculations with explicit use of the unsynchronized resonance structures introduced...
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Relativistic K shell ionisation of heavy atoms by electron impact: use of a relativistic helium-like bound state wave function
The effect of the correlation between the two K shell electrons on the relativistic triple differential cross section of the simple K shell...
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Fine-structure analysis of the (5d+6s)5 levels of Ta I
The fine structure of the prominent even levels of the neutral tantalum atom has been analyzed by simultaneous parametrization of one- and two-body...
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Interference effects in Stark spectra of weakly autoionising 5dnf states of barium
Weakly autoionising 5 d 3/2 nf Rydberg states of barium around n = 60 have been studied in the presence of a static electric field. The experiment has...
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Adiabatic population transfer by acoustooptically modulated laser beams
We demonstrate coherent two-photon optical population transfer ( STIRAP , J. Chem. Phys. 92 , 5363 (1990)) between electronic states of atoms by use of...
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The Lamb shift of excited S-levels in hydrogen and deuterium atoms
A specific combination of s -state Lamb shift Δ E L (1 s 1/2 )- n 3 Δ E L ( ns 1/2 ) is considered. Its value is calculated both in the hydrogen and deuterium...
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Total cross sections of electron collisions with S atoms; H2S, OCS and SO2 molecules (Ei ≥ 50 eV)
Collisions of intermediate to high energy electrons are considered with S-atoms as well as H 2 S, OCS and SO 2 molecules as targets. We employ e - atom...
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Measurement of dispersive properties in atomic sodium with an improved Mach-Zehnder interferometer
We report the experimental results of the absorption spectra and the dispersive properties of atomic sodium in the vicinity of 589.0 nm when an...
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Study of the hyperfine structure of Titanium atom by laser induced fluorescence on an atomic beam
Within the framework of systematic hyperfine structure (hfs) investigation of titanium atom the hfs splitting of 3 d 3 4 s 3 H 4,5,6 levels for two stable...
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Laser-Rf double-resonance measurements of the metastable 3d 34s 5P1,2,3, 3d 24s 2 1 G 4 states of 47Ti
The hyperfine structure (hfs) of 4 metastable states of 47 Ti has been measured very precisely by a laser-rf double resonance method. The...
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Calculation of avoided crossings for highly excited Stark states of Rb
Using the method of diagonalization, in which zero-field wavefunctions from a potential model are chosen as a basis, we calculate positions and...
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Spectroscopic properties of the Ar
2 * (5p) excimer statesThe transitions between Ar
2 * (5p) and Ar2 * (4s Σ u ) have been investigated by absorption spectrometry. The fine structure of the Ar... -
Doubly charged sodium clusters: plasmon response and photoproduction
The optical response of doubly charged sodium clusters Na
n +2 ++ was measured for n = 20, 40, and 58 valence electrons, for which the jellium model... -
An efficient and robust integration scheme for the equations of motion of the multiconfiguration time-dependent Hartree (MCTDH) method
An efficient and robust integration scheme tailored to the equations of motion of the multiconfiguration time-dependent Hartree (MCTDH) method is...
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Radiative neutralization of small clusters im**ing on solid surfaces
Light emission during the interaction of slow singly-charged clusters with solid surfaces is studied theoretically. More precisely, we consider...
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Term isotope shift of high lying odd and even energy levels of Nd II
The isotope shifts of the odd and even parity energy levels of singly-ionised neodymium (Nd II) have been evaluated using the measurements carried...