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    Catalytic properties of palladium complexes with silica-anchored phosphine ligands in vinyl exchange reaction

    Catalytic properties of Pd complexes with phosphine ligands anchored to silica have been studied. The valence state of Pd and the acidity of the alcohol were found to influence the rate of vinyl exhange. A pos...

    S. I. Chistyakov, V. A. Semikolenov… in Reaction Kinetics and Catalysis Letters (1979)

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    Effect of dentate number of anchored phosphine ligands on the composition and catalytic properties of their palladium complexes

    Mono-, di- and triphosphine ligands anchored by a Si−C bond to the surface of silica have been synthesized. Complexes of Pd(II) and Pd(O) with these ligands have been obtained. On the basis of elemental analys...

    V. A. Semikolenov, D. Kh. Mihailova… in Reaction Kinetics and Catalysis Letters (1979)

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