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Photoredox Catalysis in Nickel-Catalyzed Cross-Coupling

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Abstract

The traditional transition metal-catalyzed cross-coupling reaction, although well suited for C(sp2)–C(sp2) cross-coupling, has proven less amenable toward coupling of C(sp3)-hybridized centers, particularly using functional group tolerant reagents and reaction conditions. The development of photoredox/Ni dual catalytic methods for cross-coupling has opened new vistas for the construction of carbon–carbon bonds at C(sp3)-hybridized centers. In this chapter, a general outline of the features of such processes is detailed.

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Acknowledgments

The authors thank the National Institute of General Medical Sciences for a grant (R01 GM-113878) that has supported our research in this area. We are also grateful to Frontier Scientific and Evonik for supplying many of the materials used in our studies.

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Authors and Affiliations

  1. Instituto de Química-Universidade Federal do Rio Grande do Norte, Natal, RN, Brazil

    Livia N. Cavalcanti

  2. Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, PA, 19104-6323, USA

    Gary A. Molander

Authors
  1. Livia N. Cavalcanti
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  2. Gary A. Molander
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Corresponding author

Correspondence to Gary A. Molander.

Additional information

This article is part of the Topical Collection “Ni- and Fe-Based Cross-Coupling Reactions”; edited by “Arkaitz Correa”.

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Cavalcanti, L.N., Molander, G.A. Photoredox Catalysis in Nickel-Catalyzed Cross-Coupling. Top Curr Chem (Z) 374, 39 (2016). https://doi.org/10.1007/s41061-016-0037-z

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  • DOI: https://doi.org/10.1007/s41061-016-0037-z

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