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Synthesis and structure of Anderson cluster based organic–inorganic hybrid solid, \([\{\hbox {Cu}(2\hbox {-}pzc)(\hbox {H}_{2}\hbox {O})_{2}\}_{2}\{\hbox {H}_{7}\hbox {AlMo}_{6}\hbox {O}_{24}\}]\cdot 17\hbox {H}_{2}\hbox {O}\) and its dye adsorption properties

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Abstract

An inorganic–organic hybrid compound, namely \([\{\hbox {Cu}(2\hbox {-}pzc)(\hbox {H}_{2}\hbox {O})_{2}\}_{2}\{\hbox {H}_{7}\hbox {AlMo}_{6}\hbox {O}_{24}\}]{\cdot }17\hbox {H}_{2}\hbox {O}\) was synthesized based on Anderson–Evans cluster by the normal stirring process at room temperature. Its structure consists of metal coordination polymer covalently linked with Anderson–Evans cluster forming a 2D-sheet with void space containing water chains as determined by Single-Crystal X-ray Diffraction technique. This material owing to its void space of approx. 13 Å was utilized for adsorption of organic dyes like Methylene Blue (MB), Basic Violet 1 (BV1) and shows ultra-high uptake (more than 90%) within 5 min.

Graphical abstract:

Anderson-Evans cluster based organic-inorganic hybrid solid is reported which shows remarkable activity in adsorbtion of basic dyes namely Methylene Blue and Basic Violet 1 from their aqueous solution.

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Acknowledgements

MS acknowledges Prof. Ramanan for Single Crystal X-Ray facility at IIT Delhi. AJ thanks INST for PhD fellowship. MS appreciates the financial support from the Department of Science and Technology (DST) SB/FT/CS-091/2014 Project, and instrumental facility and infrastructural support from INST. SV thanks INST (25(1)/2015-INST) for financial support.

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  1. Institute of Nano Science and Technology, Phase 10, Sector-64, Mohali, Punjab, 160 062, India

    Arti Joshi, Sonalika Vaidya & Monika Singh

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  1. Arti Joshi
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  2. Sonalika Vaidya
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  3. Monika Singh
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Correspondence to Monika Singh.

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Joshi, A., Vaidya, S. & Singh, M. Synthesis and structure of Anderson cluster based organic–inorganic hybrid solid, \([\{\hbox {Cu}(2\hbox {-}pzc)(\hbox {H}_{2}\hbox {O})_{2}\}_{2}\{\hbox {H}_{7}\hbox {AlMo}_{6}\hbox {O}_{24}\}]\cdot 17\hbox {H}_{2}\hbox {O}\) and its dye adsorption properties. J Chem Sci 131, 7 (2019). https://doi.org/10.1007/s12039-018-1583-4

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