Abstract
Zirconium(IV) tungstoiodophosphate has been synthesized under a variety of conditions. The most chemically and thermally stable sample is prepared by adding a mixture of aqueous solutions of 0·5 mol L−1 sodium tungstate, potassium iodate and 1 mol L−1 orthophosphoric acid to aqueous solution of 0·1 mol L−1 zirconium(IV) oxychloride. Its ion exchange capacity for Na+ and K+ was found to be 2·20 and 2·35 meq g−1 dry exchanger, respectively. The material has been characterized on the basis of chemical composition, pH titration, Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis. The effect on the exchange capacity of drying the exchanger at different temperatures has been studied. The analytical importance of the material has been established by quantitative separation of Pb2+ from other metal ions.
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References
Alberti G, Torraca E and Conte A 1966 J. Inorg. Nucl. Chem. 28 607
Choube U N and Turel Z R 2003 Czech. J. Phys. 53 539
Clearfield A and Wang Z 2002 J. Chem. Soc. Dalton Trans. 7 2937
Davis M 1963 Infrared spectroscopy and molecular structure (Amsterdam: Elsevier Publishing Co.) p. 145
Ferragina C, Cafarelli P, Di Stefanis A, Di Rocco R and Giannoccaro P 2001 Mater. Res. Bull. 36 1799
Gupta A P and Varshney P K 1997 React. Funct. Polym. 32 67
Gupta A P, Verma G L and Ikram S 2000 React. Funct. Polym. 43 31
Hafez M A, Kenway I M M, Akl M A and Lshein R R 2001 Talanta 53 749
Hayshi H, Onoda Y and Iwasaki T 2002 Nippon Ion Kokan Gakkaishi 11 32
Jaimez E, Robert C T and Slade 1997 J. Chem. Soc. Dalton Trans. 8 1435
Mittal S K and Singh P P 1995 Indian J. Chem. A34 1009
Nabi S A and Siddiqui W A 1986 Bull. Chem. Soc. Jpn 59 2003
Nabi S A, Usmani S and Rehman N 1996 Ann. Chim. Fr. 21 521
Qureshi S Z and Rehman N 1987a Bull. Chem. Soc. Fr. 6 959
Qureshi S Z and Rehman N 1987b Bull. Chem. Soc. Jpn 60 2627
Qureshi S Z, Khan M A and Rehman N 1995 Bull. Chem. Soc. Jpn 68 1611
Qureshi S Z, Jamhour R M A Q and Rehman N 1996 Ann. Chim. (Paris) 21 609
Rao C N R 1963 Chemical application of infrared spectroscopy (New York: Academic Press)
Reilley C N, Schmid R W and Sadek F S 1959 J. Chem. Edu. 35 555
Singh P, Rawat J P and Rehman N 2002 Indian J. Chem. A41 1616
Singh P, Rawat J P and Rehman N 2003 Talanta 59 443
Sirlei R and Claudio A 1997 J. Chem. Soc. Dalton Trans. 14 2517
Socrates G 1980 Infrared characteristic group frequencies (New York: Wiley) p. 145
Tandon S, Pandit B and Chudasama U 1996 Trans. Met. Chem. 21 7
Topp N E and Pepper K W 1949 J. Chem. Soc. 3299
Varshney K G, Pandith A H and Gupta U 1998 Langmuir 14 7353
Velmurugan S, Sathyaseelam V S, Narasimhan S V and Mathur P K 1991 New development in ion exchange, in Proceedings of international conference ion exchange ICIE’91, Tokyo
Weltner W Jr and McLeod D Jr 1965 J. Phys. Chem. 69 3488
Zhaong M, Damodar M, Clearfield A and Peng G 1996 Chem. Matter. 8 1333
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Siddiqui, W.A., Khan, S.A. Synthesis, characterization and ion exchange properties of zirconium(IV) tungstoiodophosphate, a new cation exchanger. Bull Mater Sci 30, 43–49 (2007). https://doi.org/10.1007/s12034-007-0008-7
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DOI: https://doi.org/10.1007/s12034-007-0008-7