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Oxidation-resistant coatings for ultra-high-temperature refractory Mo-based alloys

  • Refractory Metals
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Abstract

The synthesis of robust coatings that provide protection against environmental attack at ultra-high temperatures is a difficult challenge. In order to achieve this goal for Mo-based alloys the fundamental concepts of reactive diffusion pathway analysis and kinetic biasing are used to design a multilayer coating with a phase sequencing that provides for structural and thermodynamic compatibility and an underlying diffusion barrier to maintain coating integrity. The coating structure evolution during high-temperature exposure facilitates a prolonged lifetime as well as a self-healing capability. Both borosilicide and aluminide coatings that can be synthesized by a pack cementation process are demonstrated to yield superior environmental resistance on Mo-based systems at temperatures up to l,700°C and can be adapted to apply to other refractory metal systems.

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References

  1. J.-C. Zhao and J.H. Westbrook, MRS Bulletin, 28(9) (2003), pp. 622–627.

    CAS  Google Scholar 

  2. D.M. Dimiduk and J.H. Perepezko, MRS Bulletin, 28(9) (2003), pp. 639–645.

    CAS  Google Scholar 

  3. J.H. Perepezko, R. Sakidja, and K.S. Kumar, in Advanced Structural Materials: Properties, Design Optimization, and Applications, ed. W. Soboyejo (Boca Raton, FL: CRC Press, 2007), pp. 437–473.

    Google Scholar 

  4. J.H. Schneibel, R.O. Ritchie, J.J. Kruzic, and P.F. Tortorelli, Metall. Mater. Trans., 36A (2005), pp. 525–531.

    Article  CAS  Google Scholar 

  5. A.P. Alur, N. Chollacoop, and K.S. Kumar, Acta Material, 52 (2004), pp. 5571–5587.

    Article  CAS  Google Scholar 

  6. J.H. Perepezko, R. Sakidja, S. Kim, Z. Dong, and J.S. Park, in Third International Symposium on Structural Intermetallics (ISSI-3), ed. Kevin J. Hemker and Dennis M. Dimiduk (Warrendale, PA: TMS, 2002), pp. 505–514.

    Google Scholar 

  7. R. Sakidja and J.H. Perepezko, J. Nuclear Mater., 366 (2007), pp. 407–416.

    Article  CAS  ADS  Google Scholar 

  8. R. Sakidja, J.H. Perepezko, S. Kim, and N. Sekido, Acta Mater., 56 (2008), pp. 5223–5244.

    Article  CAS  Google Scholar 

  9. S. Kim and J.H. Perepezko, J. Phase Equilibria and Diffusion, 27(6) (2006), pp. 605–613.

    CAS  Google Scholar 

  10. M.G. Mendiratta, T.A. Parthasarathy, and D.M. Dimiduk, Intermetallics, 10 (2002), pp. 225–232.

    Article  CAS  Google Scholar 

  11. V. Supatarawanich, D.R. Johnson, and C.T. Liu, Mater. Sci. Eng. A, 344 (2003), pp. 328–339.

    Article  Google Scholar 

  12. D.M. Berczik, U.S. patents 5,595,616 (1997) and 5,693,156 (1997).

  13. J.S. Park, R. Sakidja, and J.H. Perepezko, Scripta Mater., 46 (2002), pp. 765–770.

    Article  CAS  Google Scholar 

  14. D.A. Helmick, G.H. Meier, and F.S. Petit, Metall. and Mater. Trans., 36A (2005), pp. 3371–3383.

    Article  CAS  Google Scholar 

  15. K. Yoshimi, S. Nakatani, T Suda, S. Hanada, and H. Habazaki, Intermetallics, 10 (2002), pp. 407–414.

    Article  CAS  Google Scholar 

  16. K. Yoshimi, S. Nakatani, N. Nomura, and S. Hanada, Intermetallics, 11 (2003), pp. 787–794.

    Article  CAS  Google Scholar 

  17. D.M. Shah, D. Berczik, D.L. Anton, and R. Hecht, Mater. Sci. Eng. A, 155 (1992), pp. 45–57.

    Article  Google Scholar 

  18. R. Sakidja, J.S. Park, J. Hamann, and J.H. Perepezko, Scripta Mater., 53 (2005), pp. 723–728.

    Article  CAS  Google Scholar 

  19. R. Sakidja, F. Rioult, J. Werner, and J.H. Perepezko, Scripta Mater., 55 (2006), pp. 903–906.

    Article  CAS  Google Scholar 

  20. J.H. Perepezko, J.S. Park, and R. Sakidja, U.S. patent 7,005,191 (2006).

    Google Scholar 

  21. S.R. Levine and R.M. Caves, J. Electrochem. Soc., 121 (1974), pp. 1051–1064.

    Article  CAS  Google Scholar 

  22. A. Mueller, G. Wang, R.A. Rapp, E.L. Courtright, and T.A. Kircher, Mater. Sci. Eng., A155 (1992), pp. 199–207.

    CAS  Google Scholar 

  23. B.V. Cockram and R.A. Rapp, Metall. Mater. Trans., 26A (1995), pp. 777–791.

    Article  Google Scholar 

  24. N.P. Bansal and R.H. Doremus, editors, Handbook of Glass Properties (Orlando, FL: Academic Press, 1986).

    Google Scholar 

  25. A.E. McHale and R.S. Roth, Phase Equilibria Diagrams, 12 (1996), pp. 11–12.

    Google Scholar 

  26. J.S. Kirkaldy and D.J. Young, Diffusion in the Condensed State (London: Institute of Metals, 1987).

    Google Scholar 

  27. M.K. Meyer, A.J. Thorn, and M. Akinc, Intermetallics, 7 (1999), pp. 153–162.

    Article  CAS  Google Scholar 

  28. J.H. Perepezko, M.H. da Silva Bassani, J.S. Park, A.S. Edelstein, and R.K. Everett, Mater. Sci. Eng. A, 195 (1995), pp. 1–11.

    Article  Google Scholar 

  29. M. Meyer, M.J. Kramer, and M. Akinc, Intermetallics, 4(4) (1996), pp. 273–281.

    Article  CAS  Google Scholar 

  30. M. Akinc, M.K. Meyer, M.J. Kramer, A.J. Thorn, J.J. Huebsch and B. Cook, Intermetallics, A261 (1999), pp. 16–23.

    CAS  Google Scholar 

  31. P.C. Tortorici and M.A. Dayananda, Scripta Mater., 38 (1998), pp. 1863–1869.

    Article  CAS  Google Scholar 

  32. J-K. Yoon, J-K. Lee, K-H. Lee, J-Y. Byun, G-Ho Kim, and K-T. Honga, Intermetallics, 11(7) (2003), pp. 687–696.

    Article  CAS  Google Scholar 

  33. F. Rioult, N. Sekido, R. Sakidja, and J.H. Perepezko, J. Electrochemical Society, 154(11) (2007), pp. C692–C701.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Materials Science and Engineering, University of Wisconsin-Madison, 1509 University Ave., Madison, WI, 53706, USA

    J. H. Perepezko & R. Sakidja

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  1. J. H. Perepezko
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  2. R. Sakidja
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Correspondence to J. H. Perepezko.

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Perepezko, J.H., Sakidja, R. Oxidation-resistant coatings for ultra-high-temperature refractory Mo-based alloys. JOM 62, 13–19 (2010). https://doi.org/10.1007/s11837-010-0148-x

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  • DOI: https://doi.org/10.1007/s11837-010-0148-x

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