Abstract
The adsorption of the bentonite toward Ni(II) from aqueous solution was studied to obtain optimum conditions, equilibrium model, thermodynamic and kinetic parameters. Statistical method was used to evaluate maximum amount of adsorbed Ni (II). In this work, pH of solution during stirring, contact time, initial Ni (II) concentration, particle size of bentonite and amount of bentonite were considered as effective parameters which should be examined. The increase of temperature has negative effect on the Ni(II) adsorption. The equilibrium data were correlated well with Freundlich and Dubinin–Radushkevich isotherm models the correlation coefficients of which are (R 2) 0.994 and 0.971, respectively. This model indicates heterogeneous and chemical absorption or ion exchange process. The values of thermodynamic parameters such as ΔH°, ΔS° and ΔG° of nickel adsorption reveal that it is a spontaneous, exothermic and associative process. The experimental data fit the pseudo-second-order kinetic very well with correlation coefficient (R 2) more than 0.995.
Similar content being viewed by others
References
AJMAL M, RAO R A K, AHMAD R, AHMAD J. Adsorption studies on Citrus reticulata (fruit peel of orange): removal and recovery of Ni(II) from electroplating wastewater [J]. Journal of Hazardous Materials, 2000, 79(1): 117–131.
KADIRVELU K, SENTHILKUMAR P, THAMARAISELVI K AND SUBBURAM V. Activated carbon prepared from biomass as adsorbent: Elimination of Ni(II) from aqueous solution [J]. Bioresource Technology, 2002, 81(1): 87–90.
Mc GRATH S, SMITH S. Chromium and nickel [J]. Heavy Metals in Soils, 1995, 7: 152–178.
AJMAL M, MOHAMMAD A, YOUSUF R, AHMAD A. Adsorption behaviour of cadmium, zinc, nickel and lead from aqueous solutions by Mangifera indica seed shell [J]. Indian Journal of Environmental Health, 1998, 40(1): 15–26.
GUPTA V K, JAIN C, ALI I, SHARMA M, SAINI V. Removal of cadmium and nickel from wastewater using bagasse fly ash—A sugar industry waste [J]. Water Research, 2003, 37(16): 4038–4044.
POPURI S R, VIJAYA Y, BODDU V M, ABBURI K. Adsorptive removal of copper and nickel ions from water using chitosan coated PVC beads [J]. Bioresource Technology, 2009, 100(1): 194–199.
ABOLLINO O, ACETO M, MALANDRINO M, SARZANINI C, MENTASTI E. Adsorption of heavy metals on Na-montmorillonite: Effect of pH and organic substances [J]. Water Research, 2003, 37(7): 1619–1627.
RHAZI M, DESBRIERES J, TOLAIMATE A, RINAUDO M, VOTTERO P, ALAGUI A. Contribution to the study of the complexation of copper by chitosan and oligomers [J]. Polymer, 2002, 43(4): 1267–1276.
DONAT R, AKDOGAN A, ERDEM E, CETISLI H. Thermodynamics of Pb2+ and Ni2+ adsorption onto natural bentonite from aqueous solutions [J]. Journal of Colloid and Interface Science, 2005, 286(1): 43–52.
TAHIR S, RAUF N. Thermodynamic studies of Ni (II) adsorption onto bentonite from aqueous solution [J]. The Journal of Chemical Thermodynamics, 2003, 35(12).
FUTALAN C M, KAN C C, DALIDA M L, HSIEN K J, PASCUA C, WAN M W. Comparative and competitive adsorption of copper, lead, and nickel using chitosan immobilized on bentonite [J]. Carbohydrate Polymers, 2011, 83(2): 528–536.
BHATTACHARYYA K G, GUPTA S S. Influence of acid activation on adsorption of Ni(II) and Cu(II) on kaolinite and montmorillonite: kinetic and thermodynamic study [J]. Chemical Engineering Journal, 2008, 136(1): 1–13.
LIU Z R, ZHOU S Q. Adsorption of copper and nickel on Na-bentonite [J]. Process Safety and Environmental Protection, 2010, 88(1): 62–66.
YANG S, LI J, LU Y, CHEN Y, WANG X. Sorption of Ni (II) on GMZ bentonite: Effects of pH, ionic strength, foreign ions, humic acid and temperature [J]. Applied Radiation and Isotopes, 2009, 67(9): 1600–1608.
VIEIRA M, NETO A, GIMENES M, DA SILVA M. Sorption kinetics and equilibrium for the removal of nickel ions from aqueous phase on calcined Bofe bentonite clay [J]. Journal of Hazardous Materials, 2010, 177(1): 362–371.
GUPTA S S, BHATTACHARYYA K G. Adsorption of Ni (II) on clays [J]. Journal of Colloid and Interface Science, 2006, 295(1): 21–32.
XU D, ZHOU X, WANG X. Adsorption and desorption of Ni2+ on Na-montmorillonite: Effect of pH, ionic strength, fulvic acid, humic acid and addition sequences [J]. Applied Clay Science, 2008, 39(3): 133–141.
SADEGHALVAD B, ARMAGHAN M, AZADMEHR A. Using iranian bentonite (Birjand Area) to remove cadmium from aqueous solutions [J]. Mine Water and the Environment: 1-10.
LANGMUIR I. The adsorption of gases on plane surfaces of glass, mica and platinum [J]. Journal of the American Chemical society, 1918, 40(9): 1361–1403.
THAMILARASU P, KARUNAKARAN K. Kinetic, equilibrium and thermodynamic studies on removal of Cr (VI) by activated carbon prepared from Ricinus communis seed shell [J]. The Canadian Journal of Chemical Engineering, 2013. 91(1): 9–18.
CRINI G, PEINDY H N, GIMBERT F, ROBERT C. Removal of CI Basic Green 4 (Malachite Green) from aqueous solutions by adsorption using cyclodextrin-based adsorbent: Kinetic and equilibrium studies [J]. Separation and Purification Technology, 2007, 53(1): 97–110.
OZCAN A S, ERDEM B, OZCAN A. Adsorption of Acid Blue 193 from aqueous solutions onto BTMA-bentonite [J]. Colloids and Surfaces-A-Physiochemical and Engineering Aspects, 2005, 266(1-3): 73–81.
YUH-SHAN H. Citation review of Lagergren kinetic rate equation on adsorption reactions.[J]. Scientometrics, 2004, 59(1): 171–177.
HO Y S, Mc KAY G. Pseudo-second order model for sorption processes [J]. Process Biochemistry, 1999, 34(5): 451–465.
ÖZACAR M. Equilibrium and kinetic modelling of adsorption of phosphorus on calcined alunite [J]. Adsorption, 2003, 9(2): 125–132.
JUANG R S, TSENG R L, WU F C, LEE S H. Adsorption behavior of reactive dyes from aqueous solutions on chitosan [J]. Journal of Chemical Technology and Biotechnology, 1997, 70(4): 391–399.
FREUNDLICH H. Over the adsorption in solution [J]. J phys Chem, 1906, 7(385471): 1100–1107.
TEMKIN M, PYZHEV V. Kinetics of ammonia synthesis on promoted iron catalysts [J]. Acta Physiochim, URSS, 1940, 12(3): 217–222.
KIM Y, KIM C, CHOI I, RENGARAJ S, YI J. Arsenic removal using mesoporous alumina prepared via a templating method [J]. Environmental science & technology, 2004. 38(3): 924–931.
SHAHWAN T, ERTEN H. Temperature effects in barium sorption on natural kaolinite and chlorite-illite clays [J]. Journal of Radioanalytical and Nuclear Chemistry, 2004, 260(1): 43–48.
ONYANGO M S, KOJIMA Y, AOYI O, BERNARDO E C, MATSUDA H. Adsorption equilibrium modeling and solution chemistry dependence of fluoride removal from water by trivalentcation-exchanged zeolite F-9 [J]. Journal of Colloid and Interface Science, 2004, 279(2): 341–350.
BEKTAS N, AGIM B A, KARA S. Kinetic and equilibrium studies in removing lead ions from aqueous solutions by natural sepiolite [J]. Journal of Hazardous Materials, 2004, 112(1): 115–122.
WEBER W, MORRIS J. Kinetics of adsorption on carbon from solution [J]. J Sanit Eng Div Am Soc Civ Eng, 1963, 89(17): 31–60.
JAMAN H, CHAKRABORTY D, SAHA P. A study of the thermodynamics and kinetics of copper adsorption using chemically modified rice husk [J]. CLEAN–Soil, Air, Water, 2009. 37(9): 704–711.
HO Y S. Removal of copper ions from aqueous solution by tree fern [J]. Water Research, 2003, 37(10): 2323–2330.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Sadeghalvad, B., Azadmehr, A.R. & Motevalian, H. Statistical design and kinetic and thermodynamic studies of Ni(II) adsorption on bentonite. J. Cent. South Univ. 24, 1529–1536 (2017). https://doi.org/10.1007/s11771-017-3557-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11771-017-3557-y