Abstract
This research quantitatively studied the effect of temperature on the synthesis of TiB2 particle reinforcement via a casing method in which a salts-metal reaction was involved. Experimental results showed that the yield of TiB2 reached 89.5 pct and most TiB2 particles ranged from 400 to 800 nm at 1173 K (900 °C) with a 10-minute reaction time; when the reaction time was 30 minutes, the TiB2 particles had similar yield and size distribution. At 973 K (700 °C) with a 10-minute reaction time, most TiB2 particles were less than 300 nm, whereas the yield was just 28.1 pct; as the time was prolonged to 30 minutes, some smaller-sized TiB2 particles were synthesized and the yield of TiB2 was 36.4 pct. At a higher temperature [1173 K (900 °C)], the synthesis of TiB2 mainly followed the precipitation-growth process at reaction interface. At a lower temperature [973 K (700 °C)], the precipitation-growth process and dissolution reaction between Al3Ti and AlB2 both contributed to the formation of TiB2.
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References
A. Mandal, R. Maiti, M. Chakraborty, B.S. Murty: Mater. Sci. Eng. A, 2004, vol. 386, pp. 296-300.
Y.F. Han, X.F. Liu, X.F. Bian: Composites Part A, 2002, vol. 33, pp. 133-38.
M.L. Wang, D. Chen, Z. Chen, Y. Wu, F.F. Wang, N.H. Ma, H.W. Wang: Mater. Sci. Eng. A, 2014, vol. 590, pp.246-254.
G. Han, W.Z. Zhang, G.H. Zhang, Z.J. Feng, YJ. Wang: Mater. Sci. Eng. A, 2015, vol. 633, pp. 161-168.
Z.N.Chen, T.M. Wang, Y.P. Zheng, Y.F. Zhao, H.J. kang, L. Gao: Mater. Sci. Eng. A, 2014, vol. 605, pp. 301-309.
S. Lakshmi, L. Lu, M. Gupta: J. Mater. Process. Tech., 1998, vol. 73, pp. 160-66.
T.X. Fan, G. Yang, D. Zhang: Metall. Mater. Trans. A, 2005, vol. 36, pp. 225-33.
C.F. Feng, L. Froyen: J. Mater. Sci., 2000, vol. 35, pp. 837-50.
Z.W. Liu, M. Rakita, W. Xu, X.M. Wang, Q.Y. Han: Chem. Eng. J., 2015, vol. 263, pp. 317-24.
Y. Birol: J. Alloy. Compd., 2009, vol. 480, pp. 311-14.
G.K. Sigworth: Metall. Trans. A, 1984, vol. 15, pp. 277-82.
G.P. Jones, J. Pearson: Metall. Trans. B, 1976, vol. 7, pp. 223-34.
C.D. Mayers, D.G. McCartney, G.J. Tatlock: Mater. Sci. Technol. Lond., 1993, vol. 9, pp. 97-103.
P.S. Mohanty, J.E. Gruzleski: Acta Metallurgica et Materialia., 1995, vol. 43, pp. 2001-12.
M.M. Guzowski, G.K. Sigworth, D.A. Sentner: Metall. Trans. A, 1987, vol. 18, pp. 603-19.
M. Emamy, M. Mahta, J. Rasizadeh: Compos. Sci. Technol., 2006, vol. 66, pp. 1063-66.
H.B. Michael, S. Ramabalan, I. Dinaharan, S.J. Vijay: Mater. Design., 2013, vol. 44, pp. 438-45.
T.M. Wang, Z.N. Chen, H.W. Fu, J. Xu, Y. Fu, T.J. Li: Scripta Materilia., 2011, vol. 64, pp. 1121-24.
T.M. Wang, H.W. Fu, Z.N. Chen, J. Xu, J. Zhu, F. Cao, T.J. Li: J. Alloy. Compd., 2012, vol. 511, pp. 45-49.
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Manuscript submitted February 21, 2015.
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Liu, Z., Han, Q., Huang, Z. et al. A Quantitative Study of the Synthesis of TiB2 Particles via Salts-Metal Reaction at Different Temperatures. Metall Mater Trans A 47, 916–926 (2016). https://doi.org/10.1007/s11661-015-3268-7
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DOI: https://doi.org/10.1007/s11661-015-3268-7