Abstract
The solid-liquid interface energy, σ SL , is of major importance during phase transformation. It has a strong influence on solidification morphologies and the final grain structure. The “grain boundary groove in an applied temperature gradient” method developed by Gündüz et al.[6] was found to be suitable for measuring the solid-liquid interface energy in ternary alloy systems (e.g., Al-Cu-Ag). In order to measure the solid-liquid interface energy, a radial heat flow apparatus was constructed and assembled. This apparatus ensures a stable temperature gradient for hours and leads to grain boundary grooves in chemical equilibrium. After rapid quenching, the samples were metallographically prepared and the local curvature of the grooves was analyzed. To determine the interface energy, the Gibbs–Thomson equation was used, which requires the local curvature of the grain boundary grooves and the adherent local undercooling obtained from heat flux simulations on the scale of the grooves.
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References
N. Maraşli: Doctoral Thesis, University of Oxford, Oxford, United Kingdom, 1994
N. Maraşli, J.D. Hunt: Acta Mater., 1996, vol. 44, p. 1085
M. Erol N. Maraşli K. Keşlioğlu, M. Gündüz: Scripta Mater., 2004, vol. 51 pp. 131–36
K. Keşlioğlu, N. Maraşli: Mater. Sci. Eng., A, 2004, vol. 369, pp. 294–301
N. Maraşli K. Keşlioğlu, B. Arslan: J. Cryst. Growth, 2003, vol. 247, pp. 613–22
M. Gündüz: Doctoral Thesis, University of Oxford, Oxford, United Kingdom, 1994
M. Gündüz, J.D. Hunt: Acta Metall., 1985, vol. 33 (9), pp. 1651–72
M. Gündüz, J.D. Hunt: Acta Metall., 1989, vol. 37 (7), p. 1839
V.T. Witusiewicz U. Hecht S.G. Fries, S. Rex: J. Alloys Compd., 2005, vol. 387, pp. 217–27
Y.S. Touloukian and C.Y. Ho: Thermophysical Properties of Matter, Specific Heat Metallic Elements and Alloys, The TPRC Data Series, 1970, vol. 4, p. 511
W.J. Parker R.J. Jenkins C.P Butler, G.L Abbott: J. Appl. Phys., 1961, vol. 32, p. 1679
G. Bräuer L. Dusza, B. Schulz: Interceramics, 1992, vol. 41, p. 7
L. Dusza: “Wärmetransport—Modelle zur Bestimmung der Temperaturleitfähigkeit von Werkstoffen mit der instationären Laser Flash Methode,” Wissenschaftlicher Bericht (Scientific Report) FZKA 5820, Forschungszentrum Karlsruhe GmbH, 1996
Acknowledgments
The authors express their gratitude to the German Research Foundation (Deutsche Forschungsgemeinschaft, DFG, Schwerpunktprogramm SPP 1120) for the financial support required to accomplish the studies within the DFG research focus, “Phase Transformations in Multicomponent Alloys.”
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Manuscript submitted January 21, 2007.
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Bulla, A., Carreno-Bodensiek, C., Pustal, B. et al. Determination of the Solid-Liquid Interface Energy in the Al-Cu-Ag System. Metall Mater Trans A 38, 1956–1964 (2007). https://doi.org/10.1007/s11661-007-9275-6
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DOI: https://doi.org/10.1007/s11661-007-9275-6