Abstract
By using inorganic Fe3O4 nanoparticles of different content as nucleation sites, PAn-Fe3O4 nanorods were successfully synthesized through a simple, conventional, and inexpensive one-step in-situ polymerization method. The TEM images revealed the size and morphology of the resultant nanocomposite. The EDS pattern confirmed the existence of Fe3O4 in the composite. The FT-IR spectral analysis confirmed the formation of PAn encapsulated Fe3O4 nanocomposite. With the content of Fe3O4 increasing, the conductivity of the nanocomposites gradually decreases, meanwhile, the saturation magnetization increases and reveals a super paramagnetic behavior. With controllable electrical, magnetic, and electromagnetic properties, the well-prepared nanocomposites may have the potential applications in chemical sensors, catalysis, microwave absorbing, and electro-magneto-rheological fluids, etc.
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S Miyauchi, H Abiko, Y Sorimachi, et al. Preparation of Barium Titanate-polypyrrole Compositions and Their Electrical Properties[J]. J. Appl. Polym. Sci., 1989, 37: 289–293
J G Guan, W Wang, R Z Gong, et al. One-Step Synthesis of Cobalt-Phthalocyanine/Iron Nanocomposite Particles with High Magnetic Susceptibility[J]. Langmuir, 2002, 18: 4 198–4 204
H S Kim, B H Sohn, W Lee, et al. Multifunctional Layer-by-layer Self-assembly of Conducting Polymers and Magnetic Nanoparticles[J]. Thin Solid Film, 2002, 419: 173–177
P Anilkumar, M Jayakannan. New Renewable Resource Amphiphilic Molecular Design for Size-Controlled and Highly Ordered Polyaniline Nanofibers[J]. Langmuir, 2006, 22: 5 952–5 957
X Lu, H Mao, D Chao, et al. Ultrasonic Synthesis of Polyaniline Nanotubes Containing Fe3O4 Nanoparticles[J]. J. Solid State Chem., 2006, 179: 2 609–2 615
C T Chen, Y C Chen. Fe3O4/TiO2 Core/Shell Nanoparticles as Affinity Probes for the Analysis of Phosphopeptides Using TiO2 Surface-Assisted Laser Desorption/Ionization Mass Spectrometry[J]. Anal. Chem., 2005, 77: 5 912–5 219
JCPDS Powder Diffraction File. International Center for Diffraction Data[DB]. Newtown Square, PA, 1980
D O Smith. Magnetization of a Magnetite Single Crystal Near the Curie Point[J]. Phys. Rev., 1956, 102: 959–963
B M Altura, A Gebrewold, A Zhang, et al. Preparation of Nanocrystalline Fe3O4 by γ-ray Radiation[J]. Mater. Lett., 1997, 33: 113–116
Yavuz, M K Ram, M Aldissi, et al. Synthesis and the Physical Properties of MnZn Ferrite and NiMnZn Ferrite-polyaniline Nanocomposite Particles[J]. J. Mater. Chem., 2005, 15: 810–817
W Luzny, E Banka. Relations Between the Structure and Electric Conductivity of Polyaniline Protonated with Camphorsulfonic Acid[J]. Macromolecules, 2000, 33: 425–429
Y **a, J M Wiesinger, A G Macdiarmid. Camphorsulfonic Acid Fully Doped Polyaniline Emeraldine Salt: Conformations in Different Solvents Studied by an Ultraviolet/visible/near-infrared Spectroscopic Method[J]. Chem. Mater., 1995, 7: 443–445
A B Diaz, N D S Mohallem, R D Sinisterra. Preparation of a Ferrofluid Using Cyclodextrin and Magnetite[J]. J. Magn. Magn. Mater. R., 2004, 272: 2 395–2 397
A G MacDiamid, J C Chiang, M Halpern, et al. “Polyaniline”: Interconversion of Metallic and Insulating Forms[J]. Cryst. Liq. Cryst., 1985, 121: 173–180
S Wei, Y Zhu, Y Zhang, et al. Preparation and Characterization of Hyperbranched Aromatic Polyamides/Fe3O4 Magnetic Nanocomposite[J]. React. Funct. Polym., 2006, 66: 1 272–1 277
A Bocanegra, N D S Mohallem, R D Sinisterra. Complex Material Using Beta-Cyclodextrins and Nickel-zinc Ferrite to Obtain a Magnetically Targetable Drug Carrier[J]. Mater. Res. Soc. Symp. Proc., 2002, 711: 30–35
H Q **e, J G Guan, J S Guo. Three Ways to Improve Electroheological Properties of Polyaniline-based Suspensions[J]. J. Appl. Poly. Sci., 1997, 64: 1 641–1 647
N Z Kazantseva, J Vilcakova, V Kresalek, et al. Magnetic Behaviour of Composites Containing Polyaniline-coated Manganese-zinc Ferrite[J]. J. Magn. Magn.Mater., 2004, 269: 30–37
B Tang, Y Geng, Q Sun, et al. Processible Nanomaterials with High Conductivity and Magnetizability. Preparation and Properties of Maghemite/polyaniline Nanocomposite Films[J]. Pure Appl. Chem., 2000, 72: 157–162
J Deng, C He, Y Peng, et al. Magnetic and Conductive Fe3O4-polyaniline Nanoparticles with Core-shell Structure[ J]. Synth. Met., 2003, 139: 295–301
D Y Godovsky. Device Applications of Polymer-Nanocomposites[J]. Adv. Polym. Sci., 2000, 153: 163–205
G Bidan, O Jarjayes, Fruchart J M. New Nanocomposites Based on Tailor Dressed Magnetic Particles in a Polypyrrole Matrix[J]. Adv. Mater., 1994, 6: 152–155
M Kryszewski, J K Jeszka. Nanostructured Conducting Polymer Composites-superparamagnetic Particles in Conducting Polymers[J]. Synth. Met., 1998, 94: 99–104
I Sapurina, A Y Osadchev, B Z Volchek. In-situ Polymerized Polyaniline Films: Brush-like Chain Ordering[J]. Synth. Met., 2002, 129: 29–37
M Fahlman, S Jasty, A J Epstein. Corrosion Protection of Iron/steel by Emeraldine Base Polyaniline: an X-ray Photoelectron Spectroscopy Study[J]. Synth. Met., 1997, 85: 1 323–1 326
X D Chen, X M He. The Effect of the Recess Shape on Performance Analysis of the Gas-lubricated Bearing in Optical Lithography[J]. Tribology International, 2006, 39(11): 1 336–1 341
He X M, Chen X D. The Dynamic Analysis of the Gas Lubracated Stage in Optical Lithography[J]. International Journal of Advanced Manufacturing Technology, 2007, 32(9–10): 978–984
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Funded by National Natural Science Foundation of China(No.10974148), Sub-project of State Key Development Program of Basic Research of China(Nos. 2009CB939704 and 2009CB939705
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Leng, C., Wei, J., Liu, Z. et al. Synthesis of polyaniline-Fe3O4 nanocomposites and their conductivity and magnetic properties. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 25, 760–764 (2010). https://doi.org/10.1007/s11595-010-0087-y
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DOI: https://doi.org/10.1007/s11595-010-0087-y