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Enhancement of gas-framework interaction in a metal–organic framework by cavity modification

通过孔道修饰增**金属-有机框架中的气体-骨架间相互作用

  • Letter
  • Chemistry
  • Published:
Science Bulletin

Abstract

Originated from the pore space segmentation modification of a reported metal–organic framework (MOF) (NOTT-125), a new porous MOF ZnX was obtained and characterized by single-crystal X-ray diffraction, elemental analysis, X-ray powder diffraction and TGA. The ZnX exhibits remarkable selective CO2 adsorption property compared with that of the NOTT-125, which should be attributed to the enhanced gas-framework interactions induced by the fragmented pore space in ZnX.

摘要

基于对一例已报道的金属-有机框架材料(NOTT-125)的孔道空间分割修饰,本文获得了一例新的多孔金属有机框架ZnX,并利用单晶X射线衍射,元素分析,X射线粉末衍射和热重对其进行了表征研究。性质研究表明,孔道分割修饰增**了ZnX中气体与框架间的相互作用,使得其相比于NOTT-125展现出更好的CO2选择性吸附性质。

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (21531005, 21421001, and 21290171) and Ministry of Education Innovation Team of China (IRT13022).

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Authors and Affiliations

  1. School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tian**, 300350, China

    Denglin Fu, Yuanyuan Xu, Meng Zhao, Ze Chang & **anhe Bu

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  1. Denglin Fu
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  2. Yuanyuan Xu
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  3. Meng Zhao
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  4. Ze Chang
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  5. **anhe Bu
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Correspondence to Ze Chang or **anhe Bu.

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Fu, D., Xu, Y., Zhao, M. et al. Enhancement of gas-framework interaction in a metal–organic framework by cavity modification. Sci. Bull. 61, 1255–1259 (2016). https://doi.org/10.1007/s11434-016-1133-8

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  • DOI: https://doi.org/10.1007/s11434-016-1133-8

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