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Synthesis and assembly with mesoporous silica of platinum (II) porphyrin complexes bearing carbazyl groups: Luminescent and oxygen sensing properties

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Chinese Science Bulletin

Abstract

A series of platinum meso-tetrakis [3-methyoxy-4-(N-carbazyl)n-alkyloxyphenyl]porphyrin (Pt-4Cn-TPP, n = 4, 6 and 8) are synthesized. Pt-4C4-TPP, Pt-4C6-TPP and Pt-4C8-TPP exhibit similar luminescent properties in solution and solid state. Three protonated platinum (II) porphyrins are assembled with mesoporous silica MCM-48, respectively, resulting in assembly materials Pt-4Cn-TPP4+/MCM-48 (n = 4, 6 and 8). The luminescent intensity of Pt-4Cn-TPP4+/MCM-48 can be extremely quenched by molecular oxygen with high sensitivity (I 0 II 100 > 9). The Stem-Volmer plots of these assembly materials display considerable linearity within a wide range of oxygen concentration (0 to 100%). The response time is all ⩽ 1 s and recovery time ⩽ 22 s for these assembly materials.

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Authors and Affiliations

  1. Key Laboratory for Supramolecular Structure and Materials of Ministry of Education, College of Chemistry, Jilin University, Changchun, 130012, China

    Huo Cheng, Zhang Huidong, Guo Jianhua, Zhang Hongyu, Zhang ** & Wang Yue

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  1. Huo Cheng
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  2. Zhang Huidong
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  3. Guo Jianhua
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  4. Zhang Hongyu
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  5. Zhang **
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  6. Wang Yue
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Correspondence to Zhang ** or Wang Yue.

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Huo, C., Zhang, H., Guo, J. et al. Synthesis and assembly with mesoporous silica of platinum (II) porphyrin complexes bearing carbazyl groups: Luminescent and oxygen sensing properties. CHINESE SCI BULL 51, 2327–2334 (2006). https://doi.org/10.1007/s11434-006-2111-3

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  • DOI: https://doi.org/10.1007/s11434-006-2111-3

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