Abstract
In the present study, compressive strength, pore structure, thermal behavior and microstructure characteristics of concrete containing ground granulated blast furnace slag and TiO2 nanoparticles as binder were investigated. Portland cement was replaced by different amounts of ground granulated blast furnace slag and the properties of concrete specimens were investigated. Although it negatively impacts the properties of concrete at early ages, ground granulated blast furnace slag up to 45 wt% was found to improve the physical and mechanical properties of concrete at later ages. TiO2 nanoparticles with the average particle size of 15 nm were partially added to concrete with the optimum content of ground granulated blast furnace slag and physical and mechanical properties of the specimens were measured. TiO2 nanoparticle as a partial replacement of cement up to 3 wt% could accelerate C-S-H gel formation as a result of increased crystalline Ca(OH)2 amount at the early age of hydration and hence increase compressive strength of concrete. The increased TiO2 nanoparticles’ content of more than 3 wt% may cause reduced compressive strength because of the decreased crystalline Ca(OH)2 content required for C-S-H gel formation and unsuitable dispersed nanoparticles in the concrete matrix. TiO2 nanoparticles could improve the pore structure of concrete and shift the distributed pores to harmless and less-harm pores.
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22 July 2021
This article has been retracted. Please see the Retraction Notice for more detail: https://doi.org/10.1007/s11431-021-1870-7
References
Shi C, Qian J. High performance cementing materials from industrial slags: A review. Resour Conserv Recycl, 2000, 29: 195–207
Smith M A. The economic and environmental benefits of increased use of pfa and granulated slag. Resour Policy, 1975, 1(3): 154–170
Collins R J, Ciesielski S K. Recycling and Use of Waste Materials and By-Products in Highway Construction. National Cooperative Highway Research Program Synthesis of Highway Practice 199. Washington DC: Transportation Research Board, 1994
Afrani I, Rogers C. The effects of different cementing materials and curing on concrete scaling. Cement Concrete Aggregates, 1994, 16: 132–139
Malhotra V M. Properties of fresh and hardened concrete incorporating ground granulated blast furnace slag. In: Malhotra V M, ed. Supplementary Cementing Materials for Concrete. Canada: Minister of Supply and Services, 1987. 291–336
Isozaki K. Some properties of alkali-activated slag cements. CAJ Rev, 1986: 120–123
Deng Y, Wu X, Tang M. High strength alkali-slag cement. J Nan**g Inst Chem Technol, 1989: 11(2): 1–7
Shi C, Wu X, Tang M. Hydration of alkali-slag cements at 150°C. Cem Concr Res, 1991, 21: 91–100
Deja J, Malolepszy J. Resistance of alkali-activated slag mortars to chloride solution. In: Proceedings of the Third International Conference on the Use of Fly Ash, Silica Fume, Slag and Natural Pozzolans in Concrete, SP-114, American Concrete Institute, Norway, Chicago, 1989. 1547–1561
Shi C, Shen X, Wu X, et al. Immobilization of radioactive wastes with Portland and alkali-slag cement pastes. Cemento, 1994, 91(2): 97–108
Siliceous By-products for Use in Concrete. Final Report of the 73 BSC RILEM Committee, 1988
Sohaib M M, Ahmed S A, Balaha M M. Effect of fire and cooling mode on the properties of slag mortars. Cem Concr Res, 2001, 31(11): 1533–1538
Detwiler R J, Fapohunda C A, Natale J. Use of supplementary cementing materials to increase the resistance to chloride ion penetration of concretes cured at elevated temperatures. ACI Mater J, 1994, 91(1): 63–66
Ramlochan T, Zacarias P, Thomas M D A, et al. The effect of pozzolans and slag on the expansion of mortars cured at elevated temperature: Part I expansive behaviour. Cem Concr Res, 2003, 33(6): 807–814
Bleszynski R F, Hooton R D, Thomas M D A, et al. Durability of ternary blend concretes with silica fume and blast furnace slag: Laboratory and outdoor exposure site studies. ACI Mater J, 2002, 99(5): 499–508
Qing Y, Zenan Z, Deyu K, et al. Influence of nano-SiO2 addition on properties of hardened cement paste as compared with silica fume. Constr Build Mat, 2007, 21: 539–545
Jo B W, Kim C H, Tae G H, et al. Characteristics of cement mortar with nano-SiO2 particles. Constr Build Mat, 2007, 21: 1351–1355
Jo B W, Kim C H, Lim J H. Investigations on the development of powder concrete with nano-SiO2 nanoparticles. KSCE J, 2007, 11(1): 37–42
Jo B W, Kim C H, Lim J H. Characteristics of cement mortar with nano-SiO2 particles. ACI Mater J, 2007, 104(7): 404–407
Lin K L, Chang W C, Linc D F, et al. Effects of nano-SiO2 and different ash nanoparticle sizes on sludge ash-cement mortar. J Env Manag, 2008, 8(4): 708–714
Lin D F, Lin K L, Chang W C, et al. Improvements of nano-SiO2 on sludge/fly ash mortar. Waste Manage, 2008, 28(6): 1081–1087
Shih J Y, Chang T P, Hsiao T C. Effect of nanosilica on characteriza tion of Portland cement composite. Cem Con Res, 2006, 36: 697–706
Campillo I, Guerrero A, Dolado J S, et al. Improvement of initial mechanical strength by nanoalumina in belite cements. Mater Lett, 2007, 61: 1889–1892
Li Z, Wang H, He S, et al. Investigations on the preparation and mechanical properties of the nano-alumina reinforced cement composite. Mater Lett, 2006, 60: 356–359
Li H, **ao H, Ou J. A study on mechanical and pressure-sensitive properties of cement mortar with nanophase materials. Cem Con Res, 2004, 34: 435–438
Flores-Velez L M, Dominguez O. Characterization and properties of Portland cement composites incorporating zinc-iron oxide nanoparticles. J Mater Sci, 2002, 37: 983–988
Nazari A, Riahi S. Microstructural, thermal, physical and mechanical behavior of the self compacting concrete containing SiO2 nanoparticles. Mater Sci Eng A, 2010, 527: 7663–7672
Nazari A, Riahi S. The effects of TiO2 nanoparticles on flexural damage of self-compacting concrete. Int J Damage Mech, 2010, doi: 10.1177/1056789510385262
Nazari A, Riahi S. The effect of TiO2 nanoparticles on water permeability and thermal and mechanical properties of high strength self-compacting concrete. Mater Sci Eng A, 2010, 528(2): 756–763
Nazari A. The effects of curing medium on flexural strength and water permeability of concrete incorporating TiO2 nanoparticles. Mater Struct, 2010, doi: 10.1617/s11527-010-9664-y
Nazari A, Riahi S. The effects of zinc dioxide nanoparticles on flexural strength of self-compacting concrete. Compos Part B-Eng, 2011, 42(2): 167–175
Nazari A, Riahi S. The effects of ZnO2 nanoparticles on split tensile strength of self-compacting concrete. J Exp Nanosc, 2010, doi: 10.1080/17458080.2010.524669
Nazari A, Riahi S. Limewater effects on properties of ZrO2 nanoparticle blended cementitious composite. J Compos Mater, 2010, doi: 10.1177/0021998310376118
Nazari A, Riahi S. Assessment of the effects of Fe2O3 nanoparticles on water permeability, workability, and setting time of concrete. J Compos Mater, 2010, doi: 10.1177/0021998310377945
Nazari A, Riahi S. The effects of limewater on flexural strength and water permeability of Al2O3 nanoparticles binary blended concrete. J Compos Mater, 2010, doi: 10.1177/0021998310378907
Nazari A, Riahi S. The effects of limewater on split tensile strength and workability of Al2O3 nanoparticles binary blended concrete. J Compos Mater, 2010, doi: 10.1177/0021998310378909
Nazari A, Riahi S. The effects of TiO2 nanoparticles on properties of binary blended concrete. J Compos Mater, 2010, doi: 10.1177/0021998310378910
Nazari A, Riahi S. Optimization mechanical properties of Cr2O3 nanoparticle binary blended cementitious composite. J Compos Mater, 2010, doi: 10.1177/0021998310377944
Li H, Zhang M H, Ou J P. Flexural fatigue performance of concrete containing nano-nanoparticles for pavement. Int J Fatigue, 2007, 29: 1292–1301
Li H, Zhang M H, Ou J P. Abrasion resistance of concrete containing nano-nanoparticles for pavement. Wear, 2006, 260: 1262–1266
Katyal N K, Ahluwalia S C, Parkash R. Effect of TiO2 on the hydration of tricalcium silicate. Cem Con Res, 1999, 29: 1851–1855
ASTM C150, Standard Specification for Portland Cement, Annual Book of ASTM Standards. Philadelphia, PA: ASTM, 2001
ASTM C39, Standard Test Method for Compressive Strength of Cylindrical Concrete Specimens, Philadelphia, PA: ASTM, 2001
Abell A B, Willis K L, Lange D A. Mercury intrusion porosimetry and image nalysis of cement-based materials. J Colloid Interface Sci, 1999, 211: 39–44
Tanaka K, Kurumisawa K. Development of technique for observing pores in hardened cement paste. Cem Con Res, 2002, 32: 1435–1441
Roncero J, Gettu R. Influencia de los superplastificantes en la microestructura de la pasta hidratada y en el comportamiento diferido de los morteros de cemento. Cemento Hormigón, 2002, 832: 12–28
Hans-Ërik G, Pentti P. Properties of SCC-especially early age and long term shrinkage and salt frost resistance. Proceedings of the 1st international RILEM symposium on self-compacting concrete, RILEM Publications S.A.R.L.; Stockholm, 1999. 211–225
Song H W, Byun K J, Kim S H, et al. Early-age creep and shrinkage in self-compacting concrete incorporating GGBFS. Proceedings of the 2nd international RILEM symposium on self-compacting concrete. Tokyo: COMS Engineering Corporation, 2001. 413–422
Hammer T A, Johansen K, Bjøntegaard Ø. Volume changes as driving forces to self-induced cracking of norwegian SCC. Proceedings of the 2nd international RILEM symposium on self-compacting concrete. Tokyo: COMS Engineering Corporation, 2001. 423–432
Turcry P, Loukili A. A study of plastic shrinkage of self-compacting concrete, Proceedings of the 3rd International RILEM Symposium on Self-Compacting Concrete. RILEM Publications S.A.R.L.; Reykjavik, 2003. 576–585
Heirman G, Vandewalle L. The influence of fillers on the properties of self-compacting concrete in fresh and hardened state. Proceedings of the 3rd International RILEM Symposium on Self-Compacting Concrete. RILEM Publications S.A.R.L.; Reykjavik, 2003. 606–618
Ye G, **u X, De Schutter G, et al. Influence of limestone powder as filler in SCC on hydration and microstructure of cement pastes. Cem Con Compos, 2007, 29(2): 94–102
Arya C, Xu Y. Effect of cement type on chloride binding and corrosion of steel in concrete. Cem Concr Res, 1995, 25(4): 893–902
Polder R B, de Rooij. Durability of marine concrete structures-field investigations and modeling. Heron, 2005, 50(3): 133–153
Glass G K, Reddy B, Buenfeld N R. Corrosion inhibition in concrete arising from its acid neutralization capacity. Corros Sci, 2000, 42: 1587–1598
Basheer P A M, Gilleece P R V, Long A E, et al. Monitoring electrical resistance of concretes containing alternative cementitious materials to assess their resistance to chloride penetration. Cem Concr Compos, 2002, 24: 437–449
Puertas F, Santos H, Palacios M, et al. Polycarboxylate superplasticiser admixtures: Effect on hydration, microstructure and rheological behavior. Adv Cem Res, 2005, 17(2): 77–89
Jawed J, Skalny J, Young J F. Hydration of Portland Cement. Structure and Performance of Cements. Barnes P, ed. Essex: Applied Science Publishers, 1983. 284–285
Kondo R, Yoshida K. Miscibility of special elements in tricalcium silicate and alite and the hydration properties of C3S solid solutions. 5th Int Symp on the Chem of Cement, Tokyo, I-262. 1968
Teoreanu I, Muntean M, Balusoiu H. Addition of titanium dioxide to Portland cement clinkers. Il Cemento, 1987. 497–404
Kondo R, Ueda S. Kinetics of hydration of cements. 5th Int Symp on the Chem of Cement, Part 2, 1968. 211
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Nazari, A., Riahi, S. RETRACTED ARTICLE: TiO2 nanoparticles’ effects on properties of concrete using ground granulated blast furnace slag as binder. Sci. China Technol. Sci. 54, 3109–3118 (2011). https://doi.org/10.1007/s11431-011-4421-1
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DOI: https://doi.org/10.1007/s11431-011-4421-1