Abstract
The fracturing property of liquid CO2 fracturing fluid varies greatly due to the rheology of fracturing fluid during fracturing process. The main objective of this investigation is to study the rheology property of thickened liquid CO2 by measuring the viscosity of thickened liquid CO2 in different physical parameters of this prepared thickener and explain the causes of rheological changes. The results show that thickener content, branching content, and molecular weight of a thickener for all could significantly improve the rheology of liquid CO2; the consistency coefficient K increased as they rose, but the rheological index n presented a decreased trend. Meanwhile, the mesh structure is proposed as a model to explain the rheological changes, and the large wetting angle means an excellent backflow, low reservoir damage, and low adsorption property. These results herein provide a basic reference to improve the CO2 fracturing technology and molecular design of CO2 thickener.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-021-18169-9/MediaObjects/11356_2021_18169_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-021-18169-9/MediaObjects/11356_2021_18169_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-021-18169-9/MediaObjects/11356_2021_18169_Fig3_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-021-18169-9/MediaObjects/11356_2021_18169_Fig4_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-021-18169-9/MediaObjects/11356_2021_18169_Fig5_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-021-18169-9/MediaObjects/11356_2021_18169_Fig6_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-021-18169-9/MediaObjects/11356_2021_18169_Fig7_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-021-18169-9/MediaObjects/11356_2021_18169_Fig8_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-021-18169-9/MediaObjects/11356_2021_18169_Fig9_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-021-18169-9/MediaObjects/11356_2021_18169_Fig10_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11356-021-18169-9/MediaObjects/11356_2021_18169_Fig11_HTML.png)
Similar content being viewed by others
Data availability
Not applicable.
References
Adam NK (1957) Use of the term ‘Young's Equation’for contact angles. Nature 180(4590):809–810
Cheng YC, Fu CC, Hsiao YS, Chien C, Juang R (2018) Clearance of low molecular-weight uremic toxins p-cresol, creatinine, and urea from simulated serum by adsorption. J Mol Liq 252:203–210. https://doi.org/10.1016/j.molliq.2017.12.084
Della Bona A, Shen C, Anusavice KJ (2004) Work of adhesion of resin on treated lithia disilicate-based ceramic. Dent Mater 20(4):338–344. https://doi.org/10.1016/S0109-5641(03)00126-X
Espinoza DA, Caldelas FM, Johnston KP, Bryant SL, Huh C (2010) Nanoparticle-stabilized supercritical CO2 foams for potential mobility control applications. SPE Improved Oil Recovery Symposium, Tulsa, Oklahoma, USA. https://doi.org/10.2118/129925-MS
Guo J, Li Y, Wang S (2018) Adsorption damage and control measures of slick-water fracturing fluid in shale reservoirs. Pet Explor Dev 45(2):336–342. https://doi.org/10.11698/PED.2018.02.15
Hoefling T, Stofesky D, Reid M, Beckman E, Enick RM (1992) The incorporation of a fluorinated ether functionality into a polymer or surfactant to enhance CO2-solubility. J Supercrit Fluids 5(4):237–241. https://doi.org/10.1016/0896-8446(92)90013-A
Huang Z, Shi C, Xu J, Kilic S, Enick RM, Beckman EJ (2000) Enhancement of the viscosity of carbon dioxide using styrene/fluoroacrylate copolymers. Macromolecules 33(15):5437–5442. https://doi.org/10.1021/ma992043+
Kilic S, Michalik S, Wang Y, Johnson JK, Enick RM, Beckman EJ (2003) Effect of grafted Lewis base groups on the phase behavior of model poly (dimethyl siloxanes) in CO2. Ind Eng Chem Res 42(25):6415–6424. https://doi.org/10.1021/ie030288b
Kim J, Lee M, Lee Y, Lee Y, Sung W (2018) The effect of capillary-trapped CO2 on oil recovery and CO2 sequestration during the WAG process. Energ Source Part A 40(18):2137–2143. https://doi.org/10.1080/15567036.2018.1495776
King S (1983) Liquid CO2 for the stimulation of low-permeability reservoirs. SPE/DOE Low Permeability Gas Reservoirs Symposium, Denver, Colorado, USA. https://doi.org/10.2118/11616-MS
Li Q, Cheng Y, Li Q, Ubedullah A, Liu Y, Yan C, Lei C (2018a) Development and verification of the comprehensive model for physical properties of hydrate sediment. Arab J Geosci 11:325. https://doi.org/10.1007/s12517-018-3685-1
Li B, Zheng C, Xu J, Lv Q, Shi D, Li Z (2018b) Experimental study on dynamic filtration behavior of liquid CO2 in tight sandstone. Fuel. 226:10–17. https://doi.org/10.1016/j.fuel.2018.03.163
Li Q, Wang Y, Wang X, Yu H, Li Q, Wang F, Bai H, Kobina F (2019a) An application of thickener to increase viscosity of liquid CO2 and the assessment of the reservoir geological damage and CO2 utilization. Energ Source Part A 41(3):368–377. https://doi.org/10.1080/15567036.2018.1518355
Li Q, Wang Y, Owusu AB (2019b) A modified Ester-branched thickener for rheology and wettability during CO2 fracturing for improved fracturing property. Environ Sci Pollut R 26(20):20787–20797. https://doi.org/10.1007/s11356-019-05386-6
Li Q, Liu L, Yu B (2021) Borehole enlargement rate as a measure of borehole instability in hydrate reservoir and its relationship with drilling mud density. J Pet Explor Prod Te 11(3):1185–1198. https://doi.org/10.1007/s13202-021-01097-2
Lv Q, Li Z, Li B, Zhang C, Shi D, Zheng C, Zhou T (2017) Experimental study on the dynamic filtration control performance of N2/liquid CO2 foam in porous media. Fuel 202:435–445. https://doi.org/10.1016/j.fuel.2017.04.034
O'Donnell MC, Gilfillan SMV, McDermott K, Edlmann CI (2018) Wastewater from hydraulic fracturing in the UK: assessing the viability and cost of management. Environmental Science: Water Research & Technology 4(2):325–335. https://doi.org/10.1039/C7EW90028G
Parhi P, Golas A, Barnthip N, Hyeran N, Erwin A, Vogler A (2009) Volumetric interpretation of protein adsorption: capacity scaling with adsorbate molecular weight and adsorbent surface energy. Biomaterials, 30(36): 6814-6824. https://doi.org/10.1016/j.biomaterials.2009.09.005
Raveendran P, Wallen SL (2002) Cooperative C-H···O hydrogen bonding in CO2− Lewis base complexes: implications for solvation in supercritical CO2. J Am Chem Soc 124(42):12590–12599. https://doi.org/10.1021/ja0174635
Sinal ML, Lancaster G (1987) Liquid CO2 fracturing: advantages and limitations. J Can Pet Technol 26(05):26–30
Sun X, Liang X, Wang S, Lu Y (2014) Experimental study on the rheology of CO2 viscoelastic surfactant foam fracturing fluid. J Pet Sci Eng 119(1):104–111. https://doi.org/10.1016/j.petrol.2014.04.017
Trickett K, **ng D, Enick R, Eastoe J, Hollamby MJ, Mutch KJ, Rogers SE, Heenan RK, Steytler DC (2009) Rod-like micelles thicken CO2. Langmuir 26(1):83–88. https://doi.org/10.1021/la902128g
Tsukahara T, Kayaki Y, Ikariya T, Ikeda Y (2004) 13C NMR spectroscopic evaluation of the affinity of carbonyl compounds for carbon dioxide under supercritical conditions. Angew Chem Int Ed 43(28):3719–3722. https://doi.org/10.1002/anie.200454190
Vengosh A, Jackson RB, Warner N, Darrah TH, Kondash A (2014) A critical review of the risks to water resources from unconventional shale gas development and hydraulic fracturing in the United States. Environ Sci Technol 48(15):8334–8348. https://doi.org/10.1021/es405118y
Wang Y, ** J, Bai B (2015) Wei M (2015) Study of displacement efficiency and flow behavior of foamed gel in non-homogeneous porous media. PLoS One 10(6):e0128414. https://doi.org/10.1371/journal.pone.0128414
Wang Y, Li Q, Dong W, Li Q, Wang F, Bai H, Zhang R, Ausustus BO (2018) Effect of different factors on the yield of epoxy-terminated polydimethylsiloxane and evaluation of CO2 thickening. RSC Adv 8(70):39787–39796. https://doi.org/10.1039/C8RA06430J
Wang J, Wang Z, Sun B, Gao Y, Wang X, Fu W (2019) Optimization design of hydraulic parameters for supercritical CO2 fracturing in unconventional gas reservoir. Fuel. 235:795–809. https://doi.org/10.1016/j.fuel.2018.08.078
Weaver JD, Nguyen PD, Loghry R (2011) Stabilizing fracture faces in water-sensitive shale formations. SPE Eastern Regional Meeting. Columbus, Ohio, USA. 10.2118/149218-MS
Yao Y, Wei M, Kang W (2021) A review of wettability alteration using surfactants in carbonate reservoirs. Adv Colloid and Interfac 294:102477. https://doi.org/10.1016/j.cis.2021.102477
Yao Y, Wei M, Bai B (2022) Descriptive statistical analysis of experimental data for wettability alteration with surfactants in carbonate reservoirs. Fuel 310:122110. https://doi.org/10.1016/j.fuel.2021.122110
Yin Z, Wang Y, Zhang C (2019) Study of adsorption behavior of hydroxypropyl guar gum on kaolin. Chin J Anal Chem 47(1):93–98. https://doi.org/10.19756/j.issn.0253-3820.171441
Zhang S, She Y, Gu Y (2011) Evaluation of polymers as direct thickeners for CO2 enhanced oil recovery. JChem Eng Data 56(4):1069–1079. https://doi.org/10.1021/je1010449
Zhang L, Zhou F, Zhang S, Li Z, Wang J, Wang Y (2019) Evaluation of permeability damage caused by drilling and fracturing fluids in tight low permeability sandstone reservoirs. J Pet Sci Eng 175:1122–1135. https://doi.org/10.1016/j.petrol.2019.01.031
Acknowledgements
This work was supported by the Shandong foam fluid research center in China University of Petroleum (East China).
Funding
This study was supported by Young Innovative Talents Project of Heilongjiang Bayi Agricultural University (ZRCQC202106) and the National Key Basic Research Program of China (2015CB250904).
Author information
Authors and Affiliations
Contributions
Li Qiang, Fuling Wang: Testing, data analysis, and writing -original draft preparation., Yanling Wang, Ning Xu, Juan Chen, Kobina Forson, **yan Zhang, Chenglin Zhang: reviewing, language modification and editing.
Corresponding authors
Ethics declarations
Ethics approval
Not applicable.
Consent to participate
Not applicable.
Consent for publication
Not applicable.
Competing interests
The authors declare no competing interests.
Additional information
Responsible Editor: Philippe Garrigues
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Li, Q., Wang, F., Forson, K. et al. Affecting analysis of the rheological characteristic and reservoir damage of CO2 fracturing fluid in low permeability shale reservoir. Environ Sci Pollut Res 29, 37815–37826 (2022). https://doi.org/10.1007/s11356-021-18169-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-021-18169-9