Log in

Minimization of Friction at Various Speeds Using Autonomous Viscosity Control of Nematic Liquid Crystal

  • Original Paper
  • Published:
Tribology Letters Aims and scope Submit manuscript

Abstract

To demonstrate the concept of the smart lubrication system using liquid crystal (LC) lubricant proposed by Nakano (Tribol Lett 14:17–24, 2003), the following three types of tests were performed: (1) film thickness measurements in pure rolling contacts, (2) friction coefficient measurements in rolling–sliding contacts, and (3) molecular orientation measurements in stationary cells. In all of these types of tests, a nematic LC [4-pentyl-4′-cyanobiphenyl (5CB)] and a carboxylic acid [hexadecanoic acid (HDA)] were used as the base fluid and the additive, respectively. The results of these tests confirm the following mechanism. First, surface films of the HDA additive that spontaneously adsorb onto contact surfaces induce surface anchoring, which has the effect of making 5CB molecules align themselves perpendicular to the surfaces, competing with the flow alignment of 5CB molecules and inducing an increase in the apparent viscosity of 5CB with decreasing entrainment speed. This increase in the apparent viscosity generates a constant friction coefficient region in the Stribeck curve on the left side of the minimum friction coefficient point, resulting in the minimization of friction at various speeds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (Germany)

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. De Gennes, P.G., Prost, J.: The physics of liquid crystals, 2nd edn. Clarendon Press, Oxford (1993)

    Google Scholar 

  2. Carrión, F.J., Martínez-Nicolás, G., Iglesias, P., Sanes, J., Bermúdez, M.D.: Liquid crystals in tribology. Int. J. Mol. Sci. 10, 4102–4115 (2009)

    Article  Google Scholar 

  3. Fischer, T.E., Bhattacharya, S., Salher, R., Lauer, J.L., Ahn, Y.J.: Lubrication by a smectic liquid crystal. Tribol. Trans. 31, 442–448 (1988)

    Article  Google Scholar 

  4. Ruths, M., Steinberg, S., Israelachvili, J.N.: Effects of confinement and shear on the properties of thin films of thermotropic liquid crystal. Langmuir 12, 6637–6650 (1996)

    Article  Google Scholar 

  5. Mori, S., Iwata, H.: Relationship between tribological performance of liquid crystals and their molecular structure. Tribol. Int. 29, 35–39 (1996)

    Article  Google Scholar 

  6. Barchan, G.P., Milaev, A.G., Gumenchuk, I.G.: Effect of the mesomorphic state-isotropic liquid phase transition on lubricating properties of liquid crystalline mixtures. Chem. Technol. Fuels Oils 24, 550–551 (1988)

    Article  Google Scholar 

  7. Artsyukhovich, A., Broekman, L.D., Salmeron, M.: Friction of the liquid crystal 8CB as probed by the surface forces apparatus. Langmuir 15, 2217–2223 (1999)

    Article  Google Scholar 

  8. Li, J., Wang, C., Shang, G., Xu, Q., Lin, Z., Guan, J., Bai, C.: Friction coefficients derived from apparent height variations in contact mode atomic force microscopy images. Langmuir 15, 7662–7669 (1999)

    Article  Google Scholar 

  9. Janik, J., Tadmor, R., Klein, J.: Shear of molecularly confined liquid crystals. 2. Stress anisotropy across a model nematogen compressed between sliding solid surfaces. Langmuir 17, 5476–5485 (2001)

    Article  Google Scholar 

  10. Ważyńska, B., Okowiak, J.A.: Tribological properties of nematic and smectic liquid crystalline mixtures used as lubricants. Tribol. Lett. 24, 1–5 (2006)

    Article  Google Scholar 

  11. Zhang, X., Liu, X., Zhang, X., Tian, Y., Meng, Y.: Ordering of the 7CB liquid crystal induced by nanoscale confinement and boundary lubrication. Liq. Cryst. 39, 1305–1313 (2012)

    Article  Google Scholar 

  12. Gribailo, A.P., Kupreev, M.P., Zamyatnin, V.O.: Effect of liquid crystals on lubricating properties of mineral oils. Chem. Technol. Fuels Oils 19, 342–345 (1983)

    Article  Google Scholar 

  13. Bermúdez, M.D., Martínez-Nicolás, G., Carrión-Vilches, F.J.: Tribological properties of liquid crystals as lubricant additives. Wear 212, 188–194 (1997)

    Article  Google Scholar 

  14. Shen, M., Luo, J., Wen, S., Yao, J.: Nano-tribological properties and mechanisms of the liquid crystal as an additive. Chin. Sci. Bull. 46, 1227–1232 (2001)

    Article  Google Scholar 

  15. Vekteris, V., Mokshin, V.: Tribological research of industrial oil with liquid-crystal additives. Mater. Sci. 44, 730–734 (2008)

    Article  Google Scholar 

  16. Latyshev, V.N., Novikov, V.V., Syrbu, S.A., Kolbashov, M.A.: Tribological properties of some cholesterical liquid-crystal additives. J. Frict. Wear 30, 411–414 (2009)

    Article  Google Scholar 

  17. Mokšin, V.: Investigation of technological properties of cutting fluid with liquid crystal additive. Acad. J. Manuf. Eng. 9, 89–93 (2011)

    Google Scholar 

  18. Novikov, V.V., Latyshev, V.N., Marshalov, M.S., Nuzhdina, E.E., Kolbashov, M.A.: Properties of cutting oils with additives of liquid crystals. J. Frict. Wear 32, 452–456 (2011)

    Article  Google Scholar 

  19. Mokšin, V., Vekteris, V.: Effectiveness of twisted nematic liquid crystals as water based cutting fluid additive and tap lubricant. Mechanics 17, 570–575 (2011)

    Google Scholar 

  20. Nakano, K.: Scaling law on molecular orientation and effective viscosity of liquid-crystalline boundary films. Tribol. Lett. 14, 17–24 (2003)

    Article  Google Scholar 

  21. Johnston, G.J., Wayte, R., Spikes, H.A.: The measurement and study of very thin lubricant films in concentrated contacts. Tribol. Trans. 34, 187–194 (1991)

    Article  Google Scholar 

  22. Wu, S.T., Wu, C.S., Warenghem, M., Ismaili, M.: Refractive index dispersions of liquid crystals. Opt. Eng. 32, 1775–1780 (1993)

    Article  Google Scholar 

  23. Hamrock, B.J., Dowson, D.: Ball bearing lubrication: the elastohydrodynamics of elliptical contacts. Wiley, New York (1981)

    Google Scholar 

  24. Nakano, K., Spikes, H.A.: Process of boundary film formation from fatty acid solution. Tribol. Online 7, 1–7 (2012)

    Article  Google Scholar 

  25. Cui, M., Kelly, J.R.: Temperature dependence of visco-elastic properties of 5CB. Mol. Cryst. Liq. Cryst. 331, 49–57 (1999)

    Article  Google Scholar 

  26. Kimura, Y., Nakano, K., Kato, T., Morishita, S.: Control of friction coefficient by applying electric fields across liquid crystal boundary films. Wear 175, 143–149 (1994)

    Article  Google Scholar 

Download references

Acknowledgments

This work was carried out as a part of the “Green Tribology Innovation Network” Project in the area of Advanced Environment Materials of the Green Network of Excellence (GRENE) program funded by the Ministry of Education, Culture, Sports, Science, and Technology (MEXT) in Japan.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ken Nakano.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tadokoro, C., Nihira, T. & Nakano, K. Minimization of Friction at Various Speeds Using Autonomous Viscosity Control of Nematic Liquid Crystal. Tribol Lett 56, 239–247 (2014). https://doi.org/10.1007/s11249-014-0404-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11249-014-0404-2

Keywords

Navigation