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Rh(III) Pyridinium Substituted Bipyridine Complexes as Catalysts for Arene H/D Exchange

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Abstract

This report describes the synthesis of Rh(III) complexes containing a pyridinium-substituted bipyridine ligand. The catalytic activity of these complexes in H/D exchange reactions between arenes and acetic acid-d4 has been evaluated.

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Acknowledgments

We thank the NSF for support of this work through the Center for Enabling New Technologies through Catalysis (CENTC). In addition, JBG gratefully acknowledges the National Science Foundation (Graduate Research Fellowship) and Rackham Graduate School (Murrill Memorial Scholarship) for financial support.

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Authors and Affiliations

  1. Department of Chemistry, University of Michigan, 930 N. University Avenue, Ann Arbor, MI, 48109, USA

    J. Brannon Gary, Tyler J. Carter & Melanie S. Sanford

Authors
  1. J. Brannon Gary
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  2. Tyler J. Carter
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  3. Melanie S. Sanford
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Correspondence to Melanie S. Sanford.

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Gary, J.B., Carter, T.J. & Sanford, M.S. Rh(III) Pyridinium Substituted Bipyridine Complexes as Catalysts for Arene H/D Exchange. Top Catal 55, 565–570 (2012). https://doi.org/10.1007/s11244-012-9825-z

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