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Determination of the average heat and characteristic energy from the adsorption isotherm

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Abstract

The isotherms of the total content, isosteric and average heats of adsorption, as well as characteristic energies of adsorption were determined from the isotherms of excess adsorption of carbon dioxide on six different carbon adsorbents at temperature ranging from 293 to 423 К at pressures up to 6 MPa. The average isosteric heats are in agreement with the average heats of adsorption, which were determined from the equation relating the heat of adsorption with the characteristic energy of adsorption.

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Authors and Affiliations

  1. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    A. A. Pribylov, I. A. Kalinnikova & K. O. Murdmaa

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  1. A. A. Pribylov
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  2. I. A. Kalinnikova
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  3. K. O. Murdmaa
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Correspondence to A. A. Pribylov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0972—0977, April, 2016.

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Pribylov, A.A., Kalinnikova, I.A. & Murdmaa, K.O. Determination of the average heat and characteristic energy from the adsorption isotherm. Russ Chem Bull 65, 972–977 (2016). https://doi.org/10.1007/s11172-016-1399-7

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  • DOI: https://doi.org/10.1007/s11172-016-1399-7

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