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Polymeric heterometallic CuII dimethylmalonate complexes with potassium and cadmium ions

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Abstract

A reaction of (HPiv)2Cu2(Piv)4 with dimethylmalonic acid dipotassium salt (K2Me2mal) leads to the formation of a cage coordination polymer {(μ-H2O)6K8[(μ-H2O)Cu-(μ3,κ2-Me2mal)(μ6,κ2-Me2mal)]2[Cu2(μ5,κ2-Me2mal)2(μ5,κ2-Me2mal)2]}n (1). It was found that when 1 reacted with CdSO4·8H2O in a mixture of EtOH-H2O (3: 1), the potassium ions in 1 were displaced with cadmium(ii) ions with the formation of a heterometallic 1D-polymer [(κ1-H2O)4CdCu(μ,κ2-Me2mal)2] n (2). Compounds 1 and 2 were characterized by X-ray crystallography and ESR spectroscopy.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    N. V. Zauzolkova, E. N. Zorina, A. A. Sidorov, G. G. Aleksandrov, A. S. Lermontov, V. V. Minin, A. V. Rotov, E. A. Ugolkova, N. N. Efimov, M. A. Kiskin, V. M. Novotortsev & I. L. Eremenko

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  1. N. V. Zauzolkova
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  2. E. N. Zorina
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  3. A. A. Sidorov
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Correspondence to N. V. Zauzolkova.

Additional information

Dedicated to academician of the Russian Academy of Sciences V. I. Ovcharenko on the occasion of his 60th birthday.

Based on the Materials of the International Congress on Organic Chemistry dedicated to the 150th anniversary of the Butlerov’s Theory of Structure of Organic Compounds (September 19–23, 2011, Kazan, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1404–1410, July, 2012.

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Zauzolkova, N.V., Zorina, E.N., Sidorov, A.A. et al. Polymeric heterometallic CuII dimethylmalonate complexes with potassium and cadmium ions. Russ Chem Bull 61, 1419–1425 (2012). https://doi.org/10.1007/s11172-012-0183-6

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  • DOI: https://doi.org/10.1007/s11172-012-0183-6

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