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Synthesis and photochromic properties of new nonsymmetric dihetarylethenes — indole and thiophene derivatives

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Abstract

New nonsymmetric dihetarylethenes were synthesized: 3-(5-methoxy-1,2-dimethyl-1H-indol-3-yl)-4-(3-thienyl)furan-2,5-dione and photochromic 1-alkyl-(1-aryl)-3-(5-methoxy-1,2-dimethyl-1H-indol-3-yl)-4-(3-thienyl)-1(H)-pyrrole-2,5-diones. The absence of benzoannulation in the indole moiety results in the enhancement of the efficiencies of fluorescence and photocyclization of noncyclic isomers compared to the benzoindole derivatives.

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Authors and Affiliations

  1. Institute of Physical and Organic Chemistry, Southern Federal University, 194/2 prosp. Stachki, 344090, Rostov-on-Don, Russian Federation

    N. I. Makarova, P. V. Levchenko, A. V. Metelitsa, V. S. Kozyrev, V. A. Bren’ & V. I. Minkin

  2. Southern Scientific Center, Russian Academy of Sciences, 41 prosp. Chekhova, 344006, Rostov-on-Don, Russian Federation

    E. N. Shepelenko, V. P. Rybalkin & V. I. Minkin

Authors
  1. N. I. Makarova
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  2. P. V. Levchenko
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  3. E. N. Shepelenko
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  4. A. V. Metelitsa
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  5. V. S. Kozyrev
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  6. V. P. Rybalkin
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  7. V. A. Bren’
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  8. V. I. Minkin
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Corresponding author

Correspondence to A. V. Metelitsa.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1866–1872, September, 2011.

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Makarova, N.I., Levchenko, P.V., Shepelenko, E.N. et al. Synthesis and photochromic properties of new nonsymmetric dihetarylethenes — indole and thiophene derivatives. Russ Chem Bull 60, 1899–1905 (2011). https://doi.org/10.1007/s11172-011-0286-5

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  • DOI: https://doi.org/10.1007/s11172-011-0286-5

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