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Facile synthesis of Cu-LDH with different Cu/Al molar ratios: application as antibacterial inhibitors

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Abstract

A range of Cu-LDHs has been synthesized by co-precipitation using metal nitrate precursors and sodium carbonate under varying molar ratios Cu/Al (Cu0.05–Al0.15, Cu0.10–Al0.10, Cu0.14–Al0.06, and Cu0.15–Al0.05). The uncalcined and calcined Cu-LDHs were characterized by powder X-ray diffraction and N2 adsorption–desorption. The uncalcined solids showed clear hydrotalcite-like crystalline phases having a particle measurement between 5 and 16 nm. The best structure is attributed to the sample Cu0.05–Al0.15-LDHs. The particular surface areas are ranging between 40 and 92 m2/g, while the calcined samples showed the formation of Cu and Mg oxides. The antibacterial activity of Cu-LDHs with various molar ratios Cu/Al and their calcined phases were estimated towards multiple types of bacteria (Escherichia coli, Pseudomonas aeruginosa, Enterococcus faecalis, Staphylococcus aureus, and Bacillus Subtilis). The Cu0.10–Al0.10-LDHs sample shows high activity against all types of bacteria either for calcined or uncalcined materials. The obtained results of the application of Cu-LDHs antibacterial inhibitors seem to be quite promising material in the antibacterial fields.

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Authors and Affiliations

  1. Laboratory of Physico-Chemical Studies, University Dr. Moulay Tahar, Saida, 20000, Saida, Algeria

    Hadja Alia Tabti & Noria Bouchikhi

  2. Departement of Engineering Process, Faculty of Technology, University Dr. Moulay Tahar, Saida, 20000, Saida, Algeria

    Mehdi Adjdir

  3. Institute of Functional Interfaces Section, Karlsruhe Institute of Technology (KIT), 76344, Eggenstein-Leopoldshafen, Karlsruhe, Germany

    Mehdi Adjdir

  4. Biotoxicology Pharmacognosy and Biological Valorization of Plants Laboratory, Department of Biology, Faculty of Science, University of Saïda Dr. Tahar Moulay, 20000, Saida, Algeria

    Abdelkader Ammam

  5. Laboratory of Separation and Purification Technology, Department of Chemistry, Faculty of Science, University of Tlemcen, Tlemcen, Algeria

    Baghdad Mdjahed & Brahim Guezzen

  6. Laboratory of Materials and Catalysis, Faculty of Sciences, Site I BP 89 Djillali Liabès’s University, 22000, Sidi Bel-Abbès, Algeria

    Amina Ramdani

  7. Laboratory of Applied Organic Synthesis, Faculty of Exact and Applied Sciences, University Oran1 Ahmed Ben Bella, PO Box 1524, El M’Naouer, 31000, Oran, Algeria

    Choukry Kamel Benddedouche

  8. Department of Electronics, Faculty of Technology, University of Saïda Dr. Tahar Moulay, 20000, Saida, Algeria

    Nadir Chami

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  1. Hadja Alia Tabti
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  2. Mehdi Adjdir
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Correspondence to Hadja Alia Tabti or Mehdi Adjdir.

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Tabti, H.A., Adjdir, M., Ammam, A. et al. Facile synthesis of Cu-LDH with different Cu/Al molar ratios: application as antibacterial inhibitors. Res Chem Intermed 46, 5377–5390 (2020). https://doi.org/10.1007/s11164-020-04268-8

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