SpringerLink
Log in

Sorption on as-synthesized MCM-41

  • regular
  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Mesoporous materials MCM-41 with the hexagonal arrangement of pores were obtained using dodecyltrimethylammonium bromide and octadecyltrimethylammonium bromide as templating surfactants. Adsorption of toluene and propan-1-ol on the as-synthesized MCM-41 silica samples was investigated using the TG-DTG, DTA and DSC techniques. The sorption mechanism of used adsorptives is discussed in terms of hydrophobicity of pore interior filled with template as well as pore dimensions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (Canada)

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. CT Kresge ME Leonowicz WJ Roth JC Vartuli JS Beck (1992) Nature 359 710 Occurrence Handle10.1038/359710a0 Occurrence Handle1:CAS:528:DyaK38Xms1entrs%3D

    Article  CAS  Google Scholar 

  2. JS Beck JC Vartuli WJ Roth ME Leonowicz CT Kresge KD Schmitt CT-W Chu DH Olson EW Sheppard SB McCullen JB Higgins JL Schlenker (1992) J. Am. Chem. Soc. 114 10834 Occurrence Handle10.1021/ja00053a020 Occurrence Handle1:CAS:528:DyaK38Xms1entr8%3D

    Article  CAS  Google Scholar 

  3. M Sayari P Liu M Kruk M Jaroniec (1997) Chem. Mater. 9 2499 Occurrence Handle10.1021/cm970128o Occurrence Handle1:CAS:528:DyaK2sXntFWlurY%3D

    Article  CAS  Google Scholar 

  4. N Ulagappan CNR Rao (1996) Chem. Commun. 1 2759 Occurrence Handle10.1039/cc9960002759

    Article  Google Scholar 

  5. Ch-F Cheng W Zhou J Klinowski (1996) Chem. Phys. Lett. 263 247 Occurrence Handle10.1016/S0009-2614(96)01159-1 Occurrence Handle1:CAS:528:DyaK28Xnt1Kkt78%3D

    Article  CAS  Google Scholar 

  6. M Kruk M Jaroniec M Sayari (1997) Langmuir 13 6267 Occurrence Handle10.1021/la970776m Occurrence Handle1:CAS:528:DyaK2sXmvVakur0%3D

    Article  CAS  Google Scholar 

  7. M Kruk M Jaroniec M Sayari (1997) J. Phys. Chem. 101 583 Occurrence Handle1:CAS:528:DyaK2sXmtVOq

    CAS  Google Scholar 

  8. L Chen T Horiouchi T Mori K Maeda (1999) J. Phys. Chem. 103 1216 Occurrence Handle1:CAS:528:DyaK1MXns1SitQ%3D%3D

    CAS  Google Scholar 

  9. R Denoyel MTJ Keene PL Llewellyn J Rouquerol (1999) J. Therm. Anal. Cal. 56 261 Occurrence Handle10.1023/A:1010165626343 Occurrence Handle1:CAS:528:DyaK1MXnt1GhsLo%3D

    Article  CAS  Google Scholar 

  10. SA Araujo M Ionashiro VJ Fernandes AS Araujo (2001) J. Therm. Anal. Cal. 64 801 Occurrence Handle10.1023/A:1011564916290 Occurrence Handle1:CAS:528:DC%2BD3MXkslWlu7s%3D

    Article  CAS  Google Scholar 

  11. MJB Souza AOS Silva JMFB Aquino VJ Fernandes AS Araujo (2005) J. Therm. Anal. Cal. 79 493 Occurrence Handle10.1007/s10973-005-0568-y Occurrence Handle1:CAS:528:DC%2BD2M**sFynsbc%3D

    Article  CAS  Google Scholar 

  12. F Kleitz W Schmidt F Schüth (2001) Micropor. Mesopor. Mater. 44–45 95 Occurrence Handle10.1016/S1387-1811(01)00173-1

    Article  Google Scholar 

  13. F Kleitz W Schmidt F Schüth (2003) Micropor. Mesopor. Mater. 65 1 Occurrence Handle10.1016/S1387-1811(03)00506-7 Occurrence Handle1:CAS:528:DC%2BD3sXns12qsbw%3D

    Article  CAS  Google Scholar 

  14. J Goworek A Borówka R Zaleski R Kusak (2005) J. Therm. Anal. Cal. 79 555 Occurrence Handle10.1007/s10973-005-0578-9 Occurrence Handle1:CAS:528:DC%2BD2M**sFynsLc%3D

    Article  CAS  Google Scholar 

  15. J Ryczkowski J Goworek W Gac S Pasieczna T Borowiecki (2005) Thermochim. Acta 434 2 Occurrence Handle10.1016/j.tca.2004.12.020 Occurrence Handle1:CAS:528:DC%2BD2MXmtlKjtrc%3D

    Article  CAS  Google Scholar 

  16. PJ Branton PG Hall KSW Sing (1995) Adsorption 1 77 Occurrence Handle10.1007/BF00704147 Occurrence Handle1:CAS:528:DyaK2MXksFWhtrs%3D

    Article  CAS  Google Scholar 

  17. XS Zhao Q Ma GQ Lu (1998) Energy Fuels 12 1051 Occurrence Handle10.1021/ef980113s Occurrence Handle1:CAS:528:DyaK1cXlslOmtL4%3D

    Article  CAS  Google Scholar 

  18. C Nguyen CG Sonwane SK Bhatia DD Do (1998) Langmuir 14 4950 Occurrence Handle10.1021/la971203c Occurrence Handle1:CAS:528:DyaK1cXkslGks7s%3D

    Article  CAS  Google Scholar 

  19. J-H Yun T Düren FJ Keil NA Seaton (2002) Langmuir 18 2693 Occurrence Handle10.1021/la0155855 Occurrence Handle1:CAS:528:DC%2BD38XhtVKhtL8%3D

    Article  CAS  Google Scholar 

  20. PJ Branton PA Reynolds A Studer KSW Sing JW White (1995) Adsorption 5 91 Occurrence Handle10.1023/A:1026475014012

    Article  Google Scholar 

  21. JC Vartuli A Malek WJ Roth CT Kresge SB McCullen (2001) Micropor. Mesopor. Mater. 691 44

    Google Scholar 

  22. L Mercier TJ Pinnavaia (2000) Chem. Mater. 12 188 Occurrence Handle10.1021/cm990532i Occurrence Handle1:CAS:528:DyaK1MXotFGgtro%3D

    Article  CAS  Google Scholar 

  23. M Grün KK Unger A Matsumoto K Tsutsumi et al. (1997) Characterization of Porous Solids IV The Royal Society of Chemistry London 81

    Google Scholar 

  24. EP Barrett LG Joyner PP Halenda (1951) J. Am. Chem. Soc. 73 373 Occurrence Handle10.1021/ja01145a126 Occurrence Handle1:CAS:528:DyaG3MXjsVygsg%3D%3D

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Adsorption, Maria Curie-Skłodowska University, Lublin, Poland, 20-031, M. Curie-Skłodowska sq. 3

    J. Goworek, A. Kierys & W. Stefaniak

  2. Department of General Chemistry, Maria Curie-Skłodowska University, Lublin, Poland, 20-031, M. Curie-Skłodowska sq. 3

    M. Iwan

Authors
  1. J. Goworek
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Kierys
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Iwan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. W. Stefaniak
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to J. Goworek.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Goworek, J., Kierys, A., Iwan, M. et al. Sorption on as-synthesized MCM-41. J Therm Anal Calorim 87, 165–169 (2007). https://doi.org/10.1007/s10973-006-7810-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-006-7810-0

Keywords

Search

Navigation