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Low-temperature heat capacity and thermodynamic properties of crystalline lead formate

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Abstract

As one 3-D coordination polymer, lead formate was synthesized; calorimetric study and thermal analysis for this compound were performed. The low-temperature heat capacity of lead formate was measured by a precise automated adiabatic calorimeter over the temperature range from 80 to 380 K. No thermal anomaly or phase transition was observed in this temperature range. A four-step sequential thermal decomposition mechanism for the lead formate was found through the DSC and TG-DTG techniques at the temperature range from 500 to 635 K.

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Authors and Affiliations

  1. Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, P.R. China

    J. Zhang, Y. Y. Liu, Z. H. Zhang, X. C. Lv, L. X. Sun, F. Xu, Z. C. Tan & T. Zhang

  2. Graduate School of the Chinese Academy of Sciences, Bei**g, 100049, P.R. China

    J. Zhang, Y. Y. Liu, Z. H. Zhang & X. C. Lv

  3. Department of Nanochemistry, Faculty of Engineering, Tokyo Polytechnic University, 1583 Iiyama, Atsugi, Kanagawa, 243-0297, Japan

    Y. Sawada

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  1. J. Zhang
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  2. Y. Y. Liu
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  3. Z. H. Zhang
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  4. X. C. Lv
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  5. L. X. Sun
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  6. F. Xu
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  7. Z. C. Tan
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  8. T. Zhang
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  9. Y. Sawada
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Correspondence to L. X. Sun.

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Zhang, J., Liu, Y.Y., Zhang, Z.H. et al. Low-temperature heat capacity and thermodynamic properties of crystalline lead formate. J Therm Anal Calorim 89, 643–647 (2007). https://doi.org/10.1007/s10973-006-7510-9

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  • DOI: https://doi.org/10.1007/s10973-006-7510-9

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