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PVT properties of UNEX/HCCD-PEG diluent phenyl trifluoromethyl sulfone (FS-13) and experimental measurement of vapour pressure in 283.15–363.15 K range

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Abstract

Phenyl trifluoromethyl sulfone (FS-13) is a polar diluent, proposed in literature as an alternate to nitrobenzene, in UNEX/HCCD-PEG processes for better physical properties. Its PVT properties and accurate expression for estimation of its vapour pressure are not available in the literature. Recently PVT properties of FS-13 were estimated by authors and its vapour pressure was experimentally measured at temperatures ranging from 263.15 to 363.15 K. In this paper, results of these studies are presented.

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References

  1. Luther TA, Herbst RS, Peterman DR, Tillotson RD, Garn TG, Babain VA, Smirnov IV, Stoyanov ES, Antonov NG (2006) J Radioanal Nucl Chem 267:603–613. doi:10.1007/s10967-006-0114-9

    Article  CAS  Google Scholar 

  2. ASTM Standard D4052-2009 (2003) Standard test method for density, relative density, and api gravity of liquids by digital density meter. ASTM International, West Conshohocken. doi:10.1520/D4052-09, www.astm.org

  3. ASTM Standard D1193-2006 (2003) Standard specification for reagent water. ASTM International, West Conshohocken. doi:10.1520/D1193-06, www.astm.org

  4. ASTM Standard D5191-2010 (2003) Standard test method for vapor pressure of petroleum products (mini method), ASTM International, West Conshohocken, doi:10.1520/D5191-10B, www.astm.org

  5. Marrero J, Gani R (2001) Fluid phase equilibria 183–184:183–208

    Article  Google Scholar 

  6. Kumar M, Kumar S, Sinha PK, Kamachi Mudali U Natarajan R (2011) J Radioanal Nucl Chem. doi:10.1007/s10967–011-1016-z

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Correspondence to Shekhar Kumar.

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Kumar, S., Muthukumar, M., Sinha, P.K. et al. PVT properties of UNEX/HCCD-PEG diluent phenyl trifluoromethyl sulfone (FS-13) and experimental measurement of vapour pressure in 283.15–363.15 K range. J Radioanal Nucl Chem 289, 247–249 (2011). https://doi.org/10.1007/s10967-011-1070-6

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  • DOI: https://doi.org/10.1007/s10967-011-1070-6

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