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Synthesis of Ni/H-Zr-MCM-48 and their isomerization activity of n-heptane

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Abstract

H-Zr-MCM-48 was synthesized by ion exchange from Zr-MCM-48 which was synthesized by hydrothermal method and Ni/H-Zr-MCM-48 was synthesized by impregnation method. MCM-48, Zr-MCM-48 and Ni/H-Zr-MCM-48 were characterized by various physicochemical methods including X-ray diffraction (XRD), N2 adsorption–desorption, Fourier transform infrared spectroscopy techniques and NH3 temperature programmed desorption (NH3-TPD), etc for comparison. XRD, TEM and N2 adsorption–desorption results suggest that Zr-MCM-48 samples still maintained typical cubic mesoporous framework of MCM-48, with slight decrease of specific surface areas and mesopore orders. MCM-48, Zr-MCM-48 and Ni/H-Zr-MCM-48 were also investigated by n-heptane isomerization as a probe reaction. Compared with MCM-48, Zr-MCM-48 and H-Zr-MCM-18, Ni/H-Zr-MCM-48 catalyst exhibited significantly higher selectivity for the formation of isoparaffin, with lower coke deposition and excellent catalyst stability.

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Acknowledgements

This work was supported by the Youth Fund of Northeast Petroleum University [grant number qj121608], the Cultivation Fund of Northeast Petroleum University [grant number 2017PYYL-03], and the Daqing Science and Technology Plan Projects [grant number szdfy-2015-04.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing, 163318, China

    Jian Wang, Wei Zhang, Yanhua Suo & Yingjun Wang

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  1. Jian Wang
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  2. Wei Zhang
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  3. Yanhua Suo
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  4. Yingjun Wang
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Correspondence to Wei Zhang.

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Wang, J., Zhang, W., Suo, Y. et al. Synthesis of Ni/H-Zr-MCM-48 and their isomerization activity of n-heptane. J Porous Mater 25, 1317–1324 (2018). https://doi.org/10.1007/s10934-017-0542-7

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