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Magnetic Solid-Phase Extraction of Oxadiazon and Profenofos from Environmental Water Using Magnetite Fe3O4@SiO2–C18 Nanoparticles

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Abstract

In this study, a method for extraction and preconcentration trace amounts of two organophosphorus pesticides (oxadiazon and profenofos) in environmental water was developed by using magnetic solid phase extraction followed by high performance liquid chromatography-ultraviolet detection. The Fe3O4@SiO2–C18 nanoparticles were synthesized by the chemical coprecipitation method and characterized by X-ray diffraction, scanning electron microscope, Fourier transform infrared spectroscopy, and vibrating sample magnetometer. The Fe3O4@SiO2–C18 nanoparticles were also easily separated via an external magnetic field during extraction process of oxadiazon and profenofos from environmental water. The influence of several variables including the pH of sample, sorption time, sorbent amount, eluent solvent and its volume and salt concentration in the extraction process was investigated. For this purpose, a multivariate strategy based on central composite design and desirability function was applied in order to optimize the significant variables. Under the optimum conditions, detection limits were 0.05 and 0.07 ng mL−1 for profenofos and oxadiazon, respectively. Linear dynamic ranges were achieved in the range of 0.5–10 ng mL−1 for two analytes. The relative recoveries (RR%) along with relative standard deviation (RSD%) (n = 5) were obtained to be 90 % (RSD = 9.2 %) and 86 % (RSD = 9.8 %) for oxadiazon and profenofos, respectively.

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Acknowledgments

The authors gratefully acknowledge the Department of Chemistry at Imam Hossein University and Iran Nanotechnology Initiative Council (INIC) for partial financial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Imam Hossein University, Tehran, Iran

    Bozorgmehr Maddah & Ali Sabouri

  2. Advanced Materials and Nanotechnology Research Center, Faculty of Engineering, Imam Hossein University, Tehran, Iran

    Mahdi Hasanzadeh

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  1. Bozorgmehr Maddah
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  2. Ali Sabouri
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Correspondence to Mahdi Hasanzadeh.

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Maddah, B., Sabouri, A. & Hasanzadeh, M. Magnetic Solid-Phase Extraction of Oxadiazon and Profenofos from Environmental Water Using Magnetite Fe3O4@SiO2–C18 Nanoparticles. J Polym Environ 25, 770–780 (2017). https://doi.org/10.1007/s10924-016-0859-3

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