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Synthesis of Segmented Polyurethane Based on Polymeric Soybean Oil Polyol and Poly (Ethylene Glycol)

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Abstract

Polyurethane (PUR) plastic sheets were prepared by reacting hydroxylated polymeric soybean oil (PSbOH) synthesized from autoxidized soybean oil with polyethylene glycol (PEG) in the presence of isophorone diisocyanate (IPDI). FTIR technique was used to identify of chemical reactions. These polyurethanes have different valuable properties, determined by their chemical composition. The effect of stoichiometric balance (i.e., PSbOH/PEG-2000/IPDI weight ratio) on the final properties was evaluated. The polyurethane plastic sheets with the PSbOH/PEG-2000/IPDI weight ratio 1.0/1.0/0.67 and 1.0/0.3/0.3 had excellent mechanical properties indicating elongation at break more than 200%. Increase in IPDI and decrease in PEG weight ratio cause the higher stress–strain value. The properties of the materials were measured by differential scanning calorimetry (DSC), thermo gravimetric analysis (TGA), stress–strain measurements and FTIR technique.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Arts and Sciences, Zonguldak Karaelmas University, 67100, Zonguldak, Turkey

    Elif Keleş & Baki Hazer

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  1. Elif Keleş
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  2. Baki Hazer
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Correspondence to Baki Hazer.

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Keleş, E., Hazer, B. Synthesis of Segmented Polyurethane Based on Polymeric Soybean Oil Polyol and Poly (Ethylene Glycol). J Polym Environ 17, 153–158 (2009). https://doi.org/10.1007/s10924-009-0132-0

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  • DOI: https://doi.org/10.1007/s10924-009-0132-0

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