A review on selected normal-state and superconducting properties of the quasi-two-dimensional organic superconductors is given. Thereby, the focus is laid on the charge-transfer salts based on bisethylenedithio-tetrathiafulvalene, or ET for short, the building block of most of the to-date known organic superconductors. Some basic features of the crystallographic structure, the highly anisotropic electronic band structure for some materials, as well as unusual electronic-transport properties are highlighted. The principal phase diagram of the κ-phase salts and the fundamental difficulties of a purely electronic explanation of the observed features are discussed. A brief overview on the anisotropic superconducting properties as well as the still very controversial notion on the nature of the superconducting state is presented.
Similar content being viewed by others
References
Little W.A. (1964). Phys. Rev. A 134: 1416
http://nobelprize.org/chemistry/laureates/2000/
Jérome D., Mazaud A., Ribault M., Bechgaard K. (1980). J. Phys. Lett. 41: L95
T. Ishiguro, K. Yamaji, and G. Saito, in Organic Superconductors, Springer, Berlin (1998).
Jérome D. (2004). Chem. Rev. 104: 5565
M. Lang and J. Müller, in The Physics of Superconductors, K.H. Bennemann and J.B. Ketterson, eds., Springer, Berlin Heidelberg New York (2004), Vol. II, p. 453.
M. B. Maple, E. D. Bauer, V. S. Zapf, and J. Wosnitza, in The Physics of Superconductors, K. H. Bennemann and J. B. Ketterson, eds., Springer, Berlin Heidelberg New York (2004), Vol. II, p. 555.
For a recent review see: H. Kobayashi, H. Cui, and A. Kobayashi, Chem. Rev. 104, 5265 (2004).
Lang M. (1996). Supercond. Rev. 2: 1
McKenzie R.H. (1997). Science 278: 820
McKenzie R.H. (1998). Comments Cond. Mat. Phys. 18: 309
Wosnitza J. (1999). Physica C 317–318: 98
Wosnitza J. (1999). J. Low Temp. Phys. 117: 1701
Lee I.J., Brown S.E., Clark W.G., Strouse M.J., Naughton M.J., Kang W., Chaikin P.M. (2002). Phys. Rev. Lett. 88: 017004
Singleton J., Mielke C. (2002). Contemp. Phys. 43: 63
Miyagawa K., Kanoda K., Kawamoto A. (2004). Chem. Rev. 104: 5635
Williams J.M., Kini A.M., Wang H.H., Carlson K.D., Geiser U., Montgomery L.K., Pyrka G.J., Watkins D.M., Kommers J.M. Boryschuk S.J., Crouch A.V.S., Kwok W.K., Schirber J.E., Overmyer D.L., Jung D., Whangbo M.H. (1990). Inorg. Chem. 29: 3272
J. Wosnitza, in Fermi Surfaces of Low-Dimensional Organic Metals and Superconductors, Springer, Berlin Heidelberg New York (1996).
Mori T., Kobayashi A., Sasaki Y., Kobayashi H., Saito G., Inokuchi H. (1984). Chem. Lett. 1984: 957
Kartsovnik M.V., Laukhin V.N., Pesotskii S.I., Schegolev I.F., Yakovenko V.M. (1992). J. Phys. I France 2: 89
Wosnitza J., Goll G., Beckmann D., Wanka S., Schweitzer D., Strunz W. (1996). J. Phys. I (France) 6: 1597
Kartsovnik M.V. (2004). Chem. Rev. 104: 5737
Kobayashi H., Kato R., Kobayashi A., Nishio Y., Kajita K., Sasaki W. (1986). Chem. Lett. 1986: 789–833
Oshima K., Mori T., Inokuchi H., Urayama H., Yamochi H., Saito G. (1988). Phys. Rev. B 38: 938
Mori H., Tanaka S., Oshima M., Saito G., Mori T., Murayama Y., Inokuchi H. (1990). Bull. Chem. Soc. Jpn. 63: 2183
M. V. Kartsovnik, D. Andres, and W. Biberacher, C. R. Chimie, in press.
Singleton J. (2000). Rep. Prog. Phys. 63: 1111
Beckmann D., Wanka S., Wosnitza J., Schlueter J.A., Williams J.M., Nixon P.G., Winter R.W., Gard G.L., Ren J., Whangbo M.-H. (1998). Eur. Phys. J. B 1: 295
Beckmann D., Wanka S., Wosnitza J., Schweitzer D., Strunz W. (1997). Z. Phys. B 104: 207
McKenzie R.H., Moses P. (1998). Phys. Rev. Lett. 81: 4492
Moses P., McKenzie R.H. (1999). Phys. Rev. B 60: 7998
Hanasaki N., Kagoshima S., Hasegawa T., Osada T., Miura N. (1998). Phys. Rev. B 57: 1336
Wosnitza J., Hagel J., Qualls J.S., Brooks J.S., Balthes E., Schweitzer D., Schlueter J.A., Geiser U., Mohtasham J., Winter R.W., Gard G.L. (2002). Phys. Rev. B 65: 180506(R)
Yamaji K. (1989). J. Phys. Soc. Jpn. 58: 1520
Wosnitza J., Wanka S., Hagel J., Balthes E., Harrison N., Schlueter J.A., Kini A.M., Geiser U., Mohtasham J., Winter R.W., Gard G.L., (2000). Phys. Rev. B 61: 7383
Wosnitza J., Hagel J., Ignatchik O., Bergk B., Gvozdikov V.M., Schlueter J.A., Winter R.W., Gard G.L. (2006). J. Low Temp. Phys. 142: 327
Wosnitza J., Wanka S., Hagel J., Löhneysen H.v., Qualls J.S., Brooks J.S., Balthes E., Schlueter J.A., Geiser U., Mohtasham J., Winter R.W., Gard G.L. (2001). Phys. Rev. Lett. 86: 508
Wosnitza J., Hagel J., Meeson P.J., Bintley D., Schlueter J.A., Mohtasham J., Winter R.W., Gard G.L. (2003). Phys. Rev. B 67: 060504(R)
Maniv T., Zhuravlev V.N., Vagner I.D., Wyder P. (2001). Rev. Mod. Phys. 73: 867
V. M. Gvozdikov and J. Wosnitza, HAIT J. Sci. Eng. 1, 771 (2004); cond-mat\0502462; Physica B 359–361, 614 (2005) Low Temp. Phys. [Fiz. Niz. Temp.] 32, 152 (2006).
K. Kanoda, Hyperfine Interact. 104, 235 (1997); K. Kanoda, Physica C 282–287, 299 (1997).
Merino J., McKenzie R.H. (2000). Phys. Rev. B 61: 7996
Limelette P., Wzietek P., Florens S., Georges A., Costi T.A., Pasquier C., Jérome D., Mézière C., Batail P. (2003). Phys. Rev. Lett. 91: 016401
Strack Ch., Akinci C., Pashchenko V., Wolf B., Uhrig E., Assmus W., Lang M., Schreuer J., Wiehl L., Schlueter J.A., Wosnitza J., Schweitzer D., Müller J., Wykhoff J. (2005). Phys. Rev. B 72: 054511
Kini A.M., Geiser U., Wang H.H., Carlson K.D., Williams J.M., Kwok W.K., Vandervoort K.D., Thompsen J.E., Stupka D.L., Jung D., Whangbo M.-H. (1990). Inorg. Chem. 29: 2555
Kadowaki K., Woods S.B. (1986). Solid State Commun. 58: 507
Hagel J., Wosnitza J., Pfleiderer C., Schlueter J.A., Mohtasham J., Gard G.L. (2003). Phys. Rev. B 68: 104504
M. Weger, J. Low Temp. Phys. 95, 131 (1994); M. Weger and D. Schweitzer, Synth. Met. 70, 889 (1995).
M. Lang, F. Steglich, N. Toyota, and T. Sasaki, Phys. Rev. B 49, 15 227 (1994).
Hagel J., Wanka S., Beckmann D., Wosnitza J., Schweitzer D., Strunz W., Thumfart M. (1997). Physica C 291: 213
Wanka S., Beckmann D., Wosnitza J., Balthes E., Schweitzer D., Strunz W., Keller H.J. (1996). Phys. Rev. B 53: 9301
P. Müller, in it Advances in Solid State Physics, Vieweg, Braunschweig (1994).
Wanka S., Hagel J., Wosnitza J., Schweitzer D. (1999). Synth. Met. 103: 1996
Tinkham M. (1963). Phys. Rev. 129: 2413
Tinkham M. (1975). Introduction to Superconductivity. McGraw-Hill, New York
W. E. Lawrence and S. Doniach, in Proceedings of the 12th International Conference on Low Temp. Physics, Kyoto 1970, E. Kanda, ed., Academic Press of Japan, Tokyo (1971), Vol. 12, p. 361.
Uji S., Shinagawa H., Terashima T., Yakabe T., Terai Y., Tokumoto M., Kobayashi A., Tanaka H., Kobayashi H. (2001). Nature 410: 908
Balicas L., Brooks J.S., Storr K., Uji S., Tokumoto M., Tanaka H., Kobayashi H., Kobayashi A., Barzykin V., Gor’kov L.P. (2001). Phys. Rev. Lett. 87: 067002
Jaccarino V., Peter M. (1962). Phys. Rev. Lett. 9: 290
Meul H.W., Rossel C., Decroux M., Fischer Ø., Remenyi G., Briggs A. (1984). Phys. Rev. Lett. 53: 497
S. M. D. Soto, C. P. Slichter, A. M. Kini, H. H. Wang, U. Geiser, and J. M. Williams, Phys. Rev. B 52, 10 364 (1995).
Mayaffre H., Wzietek P., Jérome D., Lenoir C., Batail P. (1995). Phys. Rev. Lett. 75: 4122
Kanoda K., Miyagawa K., Kawamoto A., Nakazawa Y. (1996). Phys. Rev. B 54: 76
Kamiya S., Shimojo Y., Tanatar M.A., Ishiguro T., Yamochi H., Saito G. (2002). Phys. Rev. B 65: 134510
J. Müller, M. Lang, F. Steglich, J. A. Schlueter, A. M. Kini, U. Geiser, J. Mohtasham, R.W. Winter, G.L. Gard, T. Sasaki, and N. Toyota, Phys. Rev. B 61, 11 739 (2000).
Kini A.M., Schlueter J.A., Ward B.H., Geiser U., Wang H.H. (2001). Synth. Met. 120: 713
A. Kawamoto, K. Miyagawa, and K. Kanoda, Phys. Rev. B 55, 14 140 (1997).
Kini A.M., Carlson K.D., Wang H.H., Schlueter J.A., Dudek J.D., Sirchio S.A., Geiser U., Lykke K.R., Williams J.M. (1996). Physica C 264: 81
Pintschovius L., Rietschel H., Sasaki T., Mori H., Tanaka S., Toyota N., Lang M., Steglich F. (1997). Europhys. Lett. 37: 627
Pedron D., Visentini G., Bozio R., Williams J.M., Schlueter J.A. (1997). Physica C 276: 1
Creuzet F., Bourbonnais C., Jérome D., Schweitzer D., Keller H.J. (1986). Europhys. Lett. 1: 467
Creuzet F., Bourbonnais C., Creuzet G., Jérome D., Schweitzer D., Keller H.J. (1986). Physica B 143: 363
Soto S.M.D., Slichter C.P., Wang H.H., Geiser U., Williams J.M. (1993). Phys. Rev. Lett. 70: 2956
D. M. Ginsberg and L. C. Hebel, in it Superconductivity, R. Parks, ed., Marcel Dekker, New York (1969), Vol. I, p. 193.
Arai T., Ichimura K., Nomura K., Takasaki S., Yamada J., Nakatsuji S., Anzai H. (2001). Phys. Rev. B 63: 104518
Izawa K., Yamaguchi H., Sasaki T., Matsuda Y. (2002). Phys. Rev. Lett. 88: 027002
Elsinger H., Wosnitza J., Wanka S., Hagel J., Schweitzer D., Strunz W. (2000). Phys. Rev. Lett. 84: 6098
Wosnitza J., Wanka S., Hagel J., Reibelt M., Schweitzer D., Schlueter J.A. (2003). Synth. Met. 133–134: 201
Wosnitza J., Liu X., Schweitzer D., Keller H.J. (1994). Phys. Rev. B 50: 12747
Wanka S., Hagel J., Beckmann D., Wosnitza J., Schlueter J.A., Williams J.M., Nixon P.G., Winter R.W., Gard G.L. (1998). Phys. Rev. B 57: 3084
Kovalev A.E., Ishiguro T., Yamada J., Takasaki S., Anzai H. (2001). JETP 92: 1035
Müller J., Lang M., Helfrich R., Steglich F., Sasaki T. (2002). Phys. Rev. B 65: 140509(R)
Varelogiannis G. (2002). Phys. Rev. Lett. 88: 117005
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Wosnitza, J. Quasi-Two-Dimensional Organic Superconductors. J Low Temp Phys 146, 641–667 (2007). https://doi.org/10.1007/s10909-006-9282-9
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10909-006-9282-9