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Comparative Studies on Polarizability, Optical Basicity and Optical Properties of Lead Borosilicate Modified with Titania

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Abstract

The authors reported the data found by FT-IR spectroscopy, ultrasonic velocities, DTA and, optical investigations of (50-x) Na2B4O7–30PbO2–20SiO2–xTiO2 where x = (0, 10, 20, 30, 40, and 45) mol%. The structure changes of these glasses will be studying by FT-IR spectra. The mechanical properties have been associated with the results of FT-IR spectra. It was noted that the ultrasonic velocities, elastic-moduli, and density physical properties of these samples increased. The obtained results will discuss in terms of structural changes due to the addition of TiO2. Optical feature spectra are recorded at room temperature. The Urbach’s energy (Eu) of the prepared samples has been estimated. Polarizability and basicity of the prepared glasses according to the refractive index and optical bandgap have been investigated. The nature of the produced glasses and glass–ceramics was examined by (XRD) analysis.

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Acknowledgements

The authors extend their appreciation to the Deanship of Scientific Research at King Khalid University for the financial support through research groups program under Grant Number (R.G.P2/86/41).

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Authors and Affiliations

  1. Department of Physics, Faculty of Science, King Khalid University, P.O. Box 9004, Abha, Saudi Arabia

    H. H. Somaily, H. Algarni & H. H. Hegazy

  2. Chemistry Department, Faculty of Science, Al-Azhar University, P.O. 71452, Assiut, Egypt

    Kh. S. Shaaban

  3. Physics Department, Faculty of Science, Al-Azhar University, P.O. 71452, Assiut, Egypt

    Sayed A. Makhlouf, H. H. Hegazy, E. A. Abdel Wahab & E. R. Shaaban

  4. Research Center for Advanced Materials Science (RCAMS), King Khalid University, P. O. Box 9004, Abha, 61413, Saudi Arabia

    H. Algarni

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Somaily, H.H., Shaaban, K.S., Makhlouf, S.A. et al. Comparative Studies on Polarizability, Optical Basicity and Optical Properties of Lead Borosilicate Modified with Titania. J Inorg Organomet Polym 31, 138–150 (2021). https://doi.org/10.1007/s10904-020-01650-2

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