Abstract
Owing to the growing development of electronics manufacturing in tandem with the need for integration of electronic devices in the smallest size available, the need for multifunctional detectors becomes an insisted demand. Hence, the present research reports the enhancement of the optical and photoelectrical properties of polyvinyl alcohol, PVA, in ultraviolet and visible light regions by incorporating brilliant green dye, BG, nanoparticles of particle size 67.5 nm in PVA matrix. The molecular and crystal structure studies of PVA-BG spin-coated films are performed for verification of the influence of the embedded BG-dye molecules in the PVA matrix. The surface morphology and roughness of PVA-BG films are inspected and revealed a smooth nature of the film with average roughness ~ 4.157 nm. Significant enhancement of PVA optical properties is detected after adding BG nanoparticles using UV–Vis–NIR spectrophotometry, where a strong absorption in the visible region has resulted. Four exciting transitions are estimated with energies ~ 1.69, 2.31, 2.96, 3.29 and 4.64 eV. These enhanced properties are exploited in fabricating MIS structure based on Ag/PVA-BG/p-Si/Al as a dual-functional detector for sensing temperature and light intensity. The sensitivity of fabricated architecture as a temperature sensor is examined in the temperature range (293–373 K) and achieved an optimized sensitivity ~ 6.67 mV/K with a coefficient of determination ~ 99.30801 at driving current ~ 100 μA. The performance of the fabricated device as a light sensor is examined under the influence of halogen lamb light in light intensity range (20–80) mW/cm2. The performance evaluation of the fabricated device as a photodetector is examined in terms of spectral responsivity, specific detectivity, linear dynamic range, signal-to-noise ratio, and ON/OFF switching behavior. The resulted values of these figures of merit parameters confirm the validity of Ag/PVA-BG/p-Si/Al to be utilized as a dual-functional sensor for light and temperature in many microelectronic circuits with stable, reliable and linear performance.
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References
O. Game, U. Singh, T. Kumari, A. Banpurkar, S. Ogale, ZnO(N)-Spiro-MeOTAD hybrid photodiode: an efficient self-powered fast-response UV (visible) photosensor. Nanoscale 6, 503–513 (2014)
F. Draghici, G. Brezeanu, G. Pristavu, R. Pascu, M. Badila, A. Pribeanu, and Emilian Ceuca, 400 °C Sensor based on Ni/4H-SiC Schottky diode for reliable temperature monitoring in industrial environments. Sensors 9, 2384–2399 (2019)
G.A. Yakaboylu, R.C. Pillai, K. Sabolsky, E.M. Sabolsky, Fabrication and thermoelectric characterization of transition metal silicide-based composite thermocouples. Sensors 18, 3759–3772 (2018)
Ö. Güllü, A. Türüt, Electronic properties of Al/DNA/p-Si MIS diode: application as temperature sensor. J. Alloys Compd. 509, 571–577 (2011)
T. Zhu, M.N. Chong, Prospects of metal-insulator–semiconductor (MIS) nanojunction structures for enhanced hydrogen evolution in photoelectrochemical cells: a review. Nano Energy 12, 347–373 (2015)
S. Alialy, H. Tecimer, H. Uslu, Ş. Altındal, A comparative study on electrical characteristics of Au/N-Si Schottky diodes, with and without Bi-doped PVA interfacial layer in dark and under illumination at Room temperature. Nanomed. Nanotechnol. 4, 1000167–1000173 (2013)
S. Demirezen, S.A. Yerişkin, A detailed comparative study on electrical and photovoltaic characteristics of Al/p-Si photodiodes with coumarin-doped PVA interfacial layer: the effect of do** concentration. Polym. Bull. 25, 256 (2019). https://doi.org/10.1007/s00289-019-02704-3
S. Boughdachi, Y. Badali, Y. Azizian-Kalandaragh, Ş. Altindal, Current-transport mechanisms of the Al/(Bi2S3-PVA Nanocomposite)/p-Si Schottky diodes in the temperature range between 220 K and 380 K. J. Electron. Mater. 47(12), 6946–6953 (2018)
Ç. Bilkan, Y. Badali, S. Fotouhi-Shablou, Y. Azizian-Kalandaragh, Ş. Altındal, On the temperature dependent current transport mechanisms and barrier inhomogeneity in Au/SnO2–PVA/n-Si Schottky barrier diodes. Appl. Phys. A 123, 560–569 (2017)
Ş. Karataş, Frequency and voltage dependent electrical and dielectric properties of Ag/nGO doped PVA/p-Si sandwich structure at room temperature. J. Sandw. Struct. Mater. 025, 256 (2019). https://doi.org/10.1177/1099636219840605
S.C. Kishorea, A. Pandurangan, Facile synthesis of carbon nanotubes and their use in the fabrication of resistive switching memory devices. RSC Adv. 4, 9905–9911 (2014)
W. Jilani, A. Bouzidi, I.S. Yahia, H. Guermazi, H.Y. Zahran, G. Saker, Effect of organic dyes on structural properties, linear optics and impedance spectroscopy of methyl orange (CI acid orange) doped polyvinyl alcohol composite thin films. J. Mater. Sci. 29, 16446–16453 (2018)
K.K. Karukstis, A.V. Gulledge, Analysis of the solvatochromic behavior of the disubstituted triphenylmethane dye brilliant green. Anal. Chem. 70, 4212–4217 (1998)
M.M. Abutalib, I.S. Yahia, Selective CUT-OFF laser filters using brilliant green-doped PMMA polymeric composite films: sensing approach. J. Mater. Sci. 29, 19798–19804 (2018)
T. Kuo, C. Jhang, C. Lin, T. Hsien, H. Hsieh, Fabrication and application of coaxial polyvinyl alcohol/chitosan nanofiber membranes. Open Phys. 15, 1004–1014 (2017)
H. Abdel-Khalek, E. Shalaan, M.A. Salam, A.M. El-Mahalawy, Effect of illumination intensity on the characteristics of Cu(acac)2/n-Si photodiode. Synth. Met. 245, 223–236 (2018)
X. Yang, L. Li, S. Shang, X. Tao, Synthesis and characterization of layer-aligned poly(vinyl alcohol)/graphene nanocomposites. Polymer 51, 3431–3435 (2010)
S. Sreeja, S. Sreedhanya, N. Smijesh, R. Philip, C.I. Muneera, Organic dye impregnated poly(vinyl alcohol) nanocomposite as an efficient optical limiter: structure, morphology and photophysical properties. J. Mater. Chem. C 1, 3851–3861 (2013)
H.S. Mansur, C.M. Sadahira, A.N. Souza, A.A.P. Mansur, FTIR spectroscopy characterization of poly (vinyl alcohol) hydrogel with different hydrolysis degree and chemically crosslinked with glutaraldehyde. Mater. Sci. Eng. C 28, 539–548 (2008)
S. Khuntia, S.K. Majumder, P. Ghosh, A pilot plant study of the degradation of Brilliant Green dye using ozone microbubbles: mechanism and kinetics of reaction. Environ. Technol. 36, 336–347 (2014)
M. Aslam, M.A. Kalyar, Z.A. Raza, Fabrication of reduced graphene oxide nanosheets doped PVA composite films for tailoring their opto-mechanical properties. Appl. Phys. A 123, 424–435 (2017)
A.K. Zak, W.H.A. Majid, M.E. Abrishami, R. Yousefi, X-ray analysis of ZnO nanoparticles by Williamson-Hall and size-strain plot Methods. Solid State Sci. 13, 251–256 (2011)
C. Tang, Y. Tian, S. Hsu, Poly(vinyl alcohol) nanocomposites reinforced with bamboo charcoal nanoparticles: mineralization behavior and characterization. Materials 8, 4895–4911 (2015)
M. Zawodzki, R. Resel, M. Sferrazza, O. Kettner, B. Friedel, Interfacial morphology and effects on device performance of organic bilayer heterojunction solar cells. ACS Appl. Mater. Interfaces 7(30), 16161–16168 (2015)
K.E. Strawhecker, E. Manias, AFM of Poly(vinyl alcohol) Crystals next to an inorganic surface. Macromolecules 34, 8475–8482 (2001)
R.K. Choubey, S. Medhekar, R. Kumar, S. Mukherjee, S. Kumar, Study of nonlinear optical properties of organic dye by Z-scan technique using He–Ne laser. J. Mater. Sci. 25, 1410–1415 (2014)
H.C. Haas, H. Husek, L.D. Taylor, On the ultraviolet absorption spectrum of polyvinyl alcohol. J. Polym. Sci. Part A 1963(1), 1215–1226 (1963)
T.E. Karam, N. Siraj, Z. Zhang, A.F. Ezzir, I.M. Warner, L.H. Haber, Ultrafast and nonlinear spectroscopy of brilliant green-based nanoGUMBOS with enhanced near-infrared emission. J. Chem. Phys. 147, 144701–144707 (2017)
M. Yoshizawa, K. Suzuki, A. Kubo, S. Saikan, Femtosecond study of S2 fluorescence in malachite green in solutions. Chem. Phys. Lett. 290, 43–48 (1998)
R K. Mohammad, L H. Aboud, A H. Jassim, in Study of molecular electronic energy levels of malachite green dye, the 7th International Conference on Applied Science and Technology (ICAST 2019) AIP Conf. Proc. (2019). https://doi.org/10.1063/1.5123092
K. Kanosue, S. Ando, Fluorescent emissions of imide compounds and end-capped polyimides enhanced by intramolecular double hydrogen bonds. Phys. Chem. Chem. Phys. 17(45), 30659–30669 (2015)
S. Medhekar, R. Kumar, S. Mukherjee, R.K. Choubey, Study of nonlinear refraction of organic dye by Z-scan technique using He–Ne laser. AIP Conf. Proc. 1512, 470–471 (2013)
J. Tauc, A. Menth, States in the gap. J. Non- cryst. Solids 8–10, 569–585 (1972)
N. Marcano, A. Singh, F. Perez, Voltage-temperature characteristics of W/N-GaAs Schottky diodes activated by the constant forward current: application as temperature sensors, in Proceedings of the second IEEE International caracas conference on devices, circuits and systems, pp. 88–91 (1998)
L. Shore, Temperature Measurement and Control, Product Catalog and Reference Guide (Cryotronics, Westerville, 1995), pp. 1–10
A. Ugur, A.G. Imer, Y.S. Ocak, Electrical and photoelectrical characterization of an organic-inorganic heterojunction based on quinolone yellow dye. Mater. Sci. Semicond. Process. 39, 569–574 (2015)
R. Marnadu, J. Chandrasekaran, S. Maruthamuthu, V. Balasubramani, P. Vivek, R. Suresh, Ultra-high photoresponse with superiorly sensitive metal insulator- semiconductor (MIS) structured diodes for UV photodetector application. Appl. Surf. Sci. 480, 308–322 (2019)
A. Tataroğlu, C. Ahmedova, G. Barim, A.G. Al-Sehemi, A. Karabulut, A.A. AlGhamdi, W.A. Farooq, F. Yakuphanoglu, Electronic and optoelectronic properties of Al/coumarin doped Pr2Se3–Tl2Se/p-Si devices. J. Mater. Sci. 29, 12561–12572 (2018)
D. Yang, D. Ma, Development of organic semiconductor photodetectors: from mechanism to applications. Adv. Opt. Mater. 7, 1800522–1800544 (2019)
M. Bednorz, G.J. Matt, E.D. Głowacki, T. Fromherz, C.J. Brabec, M.C. Scharber, H. Sitter, N.S. Sariciftci, Silicon/organic hybrid heterojunction infrared photodetector operating in the telecom regime. Org. Electron. 14, 1344–1350 (2013)
H.A. El-Khalek, M.A. Salam, F.M. Amin, Fabrication and characterization of dual-band organic/inorganic photodetector for optoelectronic applications. Curr. Appl. Phys. 19, 629–638 (2019)
S.S. Mousavi, B. Sajad, M.H. Majlesar, Fast response ZnO/PVA nanocomposite-based photodiodes modified by graphene quantum dots. Mater. Des. 162, 249–255 (2019)
A.O. Goushcha, B. Tabbert, On response time of semiconductor photodiodes. Opt. Eng. 56(9), 097101–097107 (2017)
E.S. Zaus, S. Tedde, J. Fürst, D. Henseler, G.H. Döhler, Dynamic and steady state current response to light excitation of multilayered organic photodiodes. J. Appl. Phys. 101, 044501 (2007)
V. Sukhovatkin, S. Hinds, L. Brzozowski, E.H. Sargent, Colloidal quantum dot photodetectors exploiting multiexciton generation. Science 324, 1542–1546 (2009)
H.Y. Chen, M.K. Lo, G. Yang, H.G. Monbouquette, Y. Yang, Nanoparticle-assisted high photoconductive gain in composites of polymer and fullerene. Nat. Nanotechnol. 3, 543–547 (2008)
Z. **, J. Wang, PIN architecture for ultrasensitive organic thin film photoconductors. Sci. Rep. 4, 5331–5337 (2014)
H. Tian, Y. Cao, J. Sun, J. He, Enhanced broadband photoresponse of substrate free reduced graphene oxide photodetectors. J. Mater. Chem. C 7, 46536–46544 (2017)
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Nawar, A.M., El-Mahalawy, A.M. Heterostructure device based on Brilliant Green nanoparticles–PVA/p-Si interface for analog–digital converting dual-functional sensor applications. J Mater Sci: Mater Electron 31, 3256–3273 (2020). https://doi.org/10.1007/s10854-020-02874-1
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DOI: https://doi.org/10.1007/s10854-020-02874-1