Abstract
Polysiloxane is an ideal material for the preparation of wearable and flexible electronic devices. The preparation of pressure sensor using polysiloxane with both self-healing properties and excellent mechanical properties remains a key challenge. This work reports a self-healable pressure sensor based on polysiloxane network cross-linked by dynamic Diels–Alder bonds. The self-healable polysiloxane underwent a solid–liquid–solid transformation during a self-healing process, which has been confirmed by rheology. Depending on the amount of the linear reactive polydimethylsiloxane, mechanical performance and stretchability of the self-healable polysiloxane were tunable. By incorporating graphene nanosheets into polysiloxane elastomer, we fabricated a self-healable nanocomposite with significantly improved tensile stress and excellent electromechanical property. The tensile stress of nanocomposite containing 35 wt% graphene was 1.09 MPa that was improved by more than 1700% compared to that of the elastomer, indicating a significant improvement of the tensile stress with stretchability. The prepared self-healable pressure sensor exhibits a high sensitivity of 0.765 kPa−1 and a gauge factor of 4.87, demonstrating a promising potential use in the pressure sensors.
Similar content being viewed by others
References
Fox J, Wie JJ, Greenland BW, Burattini S, Hayes W, Colquhoun HM, Mackay ME, Rowan SJ (2012) High-strength, healable, supramolecular polymer nanocomposites. J Am Chem Soc 134:5362–5368
Cordier P, Tournilhac F, Soulie-Ziakovic C, Leibler L (2008) Self-healing and thermoreversible rubber from supramolecular assembly. Nature 451:977–980
White SR, Sottos NR, Geubelle PH, Moore JS, Kessler MR, Sriram SR, Brown EN, Viswanathan S (2001) Autonomic healing of polymer composites. Nature 409:794–797
Kong F, Xu W, Zhang X, Wang X, Zhang Y, Wu J (2018) High-efficiency self-repairing anticorrosion coatings with controlled assembly microcapsules. J Mater Sci 53:12850–12859. https://doi.org/10.1007/s10853-018-2596-6
White SR, Moore JS, Sottos NR, Krull BP, Santa Cruz WA, Gergely RCR (2014) Restoration of large damage volumes in polymers. Science 344:620–623
Yoshida S, Ejima H, Yoshie N (2017) Tough elastomers with superior self-recoverability induced by bioinspired multiphase design. Adv Funct Mater 27:1701670
Szatkowski P, Pielichowska K, Blazewicz S (2017) Mechanical and thermal properties of carbon-nanotube-reinforced self-healing polyurethanes. J Mater Sci 52:12221–12234. https://doi.org/10.1007/s10853-017-1353-6
Madsen FB, Yu L, Skov AL (2016) Self-healing, high-permittivity silicone dielectric elastomer. ACS Macro Lett 5:1196–1200
Cuthbert TJ, Jadischke JJ, de Bruyn JR, Ragogna PJ, Gillies ER (2017) Self-healing polyphosphonium ionic networks. Macromolecules 50:5253–5260
Mozhdehi D, Ayala S, Cromwell OR, Guan Z (2014) Self-healing multiphase polymers via dynamic metal-ligand interactions. J Am Chem Soc 136:16128–16131
Hussain I, Sayed SM, Liu S, Yao F, Oderinde O, Fu G (2018) Hydroxyethyl cellulose-based self-healing hydrogels with enhanced mechanical properties via metal-ligand bond interactions. Eur Polym J 100:219–227
McKee JR, Appel EA, Seitsonen J, Kontturi E, Scherman OA, Ikkala O (2014) Healable, stable and stiff hydrogels: combining conflicting properties using dynamic and selective three-component recognition with reinforcing cellulose nanorods. Adv Funct Mater 24:2706–2713
Jia Y-G, Zhu XX (2015) Self-healing supramolecular hydrogel made of polymers bearing cholic acid and β-cyclodextrin pendants. Chem Mater 27:387–393
Lei ZQ, **ang HP, Yuan YJ, Rong MZ, Zhang MQ (2014) Room-temperature self-healable and remoldable cross-linked polymer based on the dynamic exchange of disulfide bonds. Chem Mater 26:2038–2046
Wan T, Chen D (2016) Synthesis and properties of self-healing waterborne polyurethanes containing disulfide bonds in the main chain. J Mater Sci 52:197–207. https://doi.org/10.1007/s10853-016-0321-x
Rao YL, Chortos A, Pfattner R, Lissel F, Chiu YC, Feig V, Xu J, Kurosawa T, Gu X, Wang C, He M, Chung JW, Bao Z (2016) Stretchable self-healing polymeric dielectrics cross-linked through metal-ligand coordination. J Am Chem Soc 138:6020–6027
**ng L, Li Q, Zhang G, Zhang X, Liu F, Liu L, Huang Y, Wang Q (2016) Self-healable polymer nanocomposites capable of simultaneously recovering multiple functionalities. Adv Funct Mater 26:3524–3531
Huang Y, Zhong M, Huang Y, Zhu M, Pei Z, Wang Z, Xue Q, **e X, Zhi C (2015) A self-healable and highly stretchable supercapacitor based on a dual crosslinked polyelectrolyte. Nat Commun 6:10310
Wang S, Liu N, Su J, Li L, Long F, Zou Z, Jiang X, Gao Y (2017) Highly stretchable and self-healable supercapacitor with reduced graphene oxide based fiber springs. ACS Nano 11:2066–2074
Wang C, Wu H, Chen Z, McDowell MT, Cui Y, Bao Z (2013) Self-healing chemistry enables the stable operation of silicon microparticle anodes for high-energy lithium-ion batteries. Nat Chem 5:1042–1048
Xu W, Huang L-B, Hao J (2017) Fully self-healing and shape-tailorable triboelectric nanogenerators based on healable polymer and magnetic-assisted electrode. Nano Energy 40:399–407
** H, Huynh TP, Haick H (2016) Self-healable sensors based nanoparticles for detecting physiological markers via skin and breath: toward disease prevention via wearable devices. Nano Lett 16:4194–4202
Tee BC, Wang C, Allen R, Bao Z (2012) An electrically and mechanically self-healing composite with pressure- and flexion-sensitive properties for electronic skin applications. Nat Nanotechnol 7:825–832
Han L, Lu X, Wang M, Gan D, Deng W, Wang K, Fang L, Liu K, Chan CW, Tang Y, Weng LT, Yuan H (2017) A Mussel-inspired conductive, self-adhesive, and self-healable tough hydrogel as cell stimulators and implantable bioelectronics. Small 13:1601916
Lei Z, Wang Q, Sun S, Zhu W, Wu P (2017) A bioinspired mineral hydrogel as a self-healable, mechanically adaptable ionic skin for highly sensitive pressure sensing. Adv Mater 29:1700321
Trung TQ, Ramasundaram S, Hwang BU, Lee NE (2016) An all-elastomeric transparent and stretchable temperature sensor for body-attachable wearable electronics. Adv Mater 28:502–509
Boland CS, Khan U, Ryan G, Barwich S, Charifou R, Harvey A, Backes C, Li Z, Ferreira MS, Möbius ME, Young RJ, Coleman JN (2016) Sensitive electromechanical sensors using viscoelastic graphene-polymer nanocomposites. Science 354:1257–1260
Jeong SH, Zhang S, Hjort K, Hilborn J, Wu Z (2016) PDMS-based elastomer tuned soft, stretchable, and sticky for epidermal electronics. Adv Mater 28:5830–5836
Yu B, Kang SY, Akthakul A, Ramadurai N, Pilkenton M, Patel A, Nashat A, Anderson DG, Sakamoto FH, Gilchrest BA, Anderson RR, Langer R (2016) An elastic second skin. Nat Mater 15:911–918
Li CH, Wang C, Keplinger C, Zuo JL, ** L, Sun Y, Zheng P, Cao Y, Lissel F, Linder C, You XZ, Bao Z (2016) A highly stretchable autonomous self-healing elastomer. Nat Chem 8:618–624
Zhao J, Xu R, Luo G, Wu J, **a H (2016) A self-healing, re-moldable and biocompatible crosslinked polysiloxane elastomer. J Mater Chem B 4:982–989
Imai Y, Itoh H, Naka K, Chujo Y (2000) Thermally reversible IPN organic − inorganic polymer hybrids utilizing the diels − alder reaction. Macromolecules 33:4343–4346
Chen X, Dam MA, Ono K, Mal A, Shen H, Nutt SR, Sheran K, Wudl F (2002) A thermally re-mendable cross-linked polymeric material. Science 295:1698–1702
Fu G, Yuan L, Liang G, Gu A (2016) Heat-resistant polyurethane films with great electrostatic dissipation capacity and very high thermally reversible self-healing efficiency based on multi-furan and liquid multi-maleimide polymers. J Mater Chem A 4:4232–4241
Tian Q, Yuan YC, Rong MZ, Zhang MQ (2009) A thermally remendable epoxy resin. J Mater Chem 19:1289–1296
Gong C, Liang J, Hu W, Niu X, Ma S, Hahn HT, Pei Q (2013) A healable, semitransparent silver nanowire-polymer composite conductor. Adv Mater 25:4186–4191
Zhang D, Dumont M-J (2018) Reprocessable 5-hydroxymethylfurfural derivative-based thermoset elastomers synthesized through the thiol-Michael and Diels–Alder reactions. J Mater Sci 53:11116–11129. https://doi.org/10.1007/s10853-018-2375-4
Rueda MM, Auscher M-C, Fulchiron R, Périé T, Martin G, Sonntag P, Cassagnau P (2017) Rheology and applications of highly filled polymers: a review of current understanding. Prog Polym Sci 66:22–53
Potts JR, Dreyer DR, Bielawski CW, Ruoff RS (2011) Graphene-based polymer nanocomposites. Polymer 52:5–25
Kim S, Do I, Drzal LT (2009) Thermal stability and dynamic mechanical behavior of exfoliated graphite nanoplatelets-LLDPE nanocomposites. Polym Compos 31:755–761
Kim I-H, Jeong YG (2010) Polylactide/exfoliated graphite nanocomposites with enhanced thermal stability, mechanical modulus, and electrical conductivity. J Polym Sci, Part B: Polym Phys 48:850–858
Acknowledgements
This work was financially supported by the National Natural Science Foundation of China (Grant No. 51673054), Harbin City Science and Technology Innovation Talent Foundation (Grant No. 2017RAYXJ003) and Shanghai Space Science and Technology Innovation Foundation (Grant No. SAST2017-114).
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Zhao, L., Jiang, B. & Huang, Y. Self-healable polysiloxane/graphene nanocomposite and its application in pressure sensor. J Mater Sci 54, 5472–5483 (2019). https://doi.org/10.1007/s10853-018-03233-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-018-03233-6