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Thermal properties and crystallization of PbO–MoO3–P2O5 glasses

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Thermal properties and crystallization of glasses from PbO–MoO3–P2O5 ternary system were studied in three compositional series (100 − x)[0.5PbO–0.5P2O5]–xMoO3 (A), 50PbO–yMoO3–(50 − y)P2O5 (B), and (50 − z)PbO–zMoO3–50P2O5 (C). Glass transition temperature, crystallization temperature, coefficient of thermal expansion, and dilatation softening temperature of the studied glasses were determined by differential thermal analysis and dilatometry. Crystallization products of annealed glass samples were investigated by X-ray diffraction and Raman spectroscopy. X-ray diffraction analysis of crystallized glasses revealed the formation of PbP2O6, Pb3P4O13, and PbMoO4 in the samples of the B series. In the series A and C in the samples with a high MoO3 content, crystalline compounds of Pb(MoO2)2(PO4)2 and (MoO2)(PO3)2, respectively, were identified. Raman spectra of crystalline samples confirmed the results of X-ray diffraction measurements and provided also information on thermal stability of glasses and formation of glass-crystalline phases in the studied glass series.

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References

  1. Zakis YR, Lusis AR, Lagzdons YL (1982) J Non-Cryst Solids 47:267

    Article  CAS  Google Scholar 

  2. Studer F, Lebail A, Raveau B (1986) J Solid State Chem 63:414

    Article  CAS  Google Scholar 

  3. Chowdari BVR, Gopalakrishnan R, Tang SH, Kuok SH (1988) Solid State Ion 28–30:704

    Article  Google Scholar 

  4. Pinet O, Dussossoz JL, David C, Fillet C (2008) J Nucl Mater 377:307

    Article  CAS  Google Scholar 

  5. Chourasia R, Shrivastava OP, Wattal PK (2009) J Alloys Comp 473:579

    Article  CAS  Google Scholar 

  6. Chowdari BVR, Tan KL, Chia WT, Gopalakrishnan R (1990) Solid State Ion 40–41:684

    Article  Google Scholar 

  7. Chowdari BVR, Tan KL, Chia WT, Gopalakrishnan R (1991) J Non-Cryst Solids 128:18

    Article  CAS  Google Scholar 

  8. Bih L, Nadiri A, El Amraoui Y (2005) J Phys IV Fr 123:165

    Article  CAS  Google Scholar 

  9. Santagneli SH, de Araujo CC, Strojek W, Eckert H, Poirier G, Ribeiro SJL, Messadeq Y (2007) J Phys Chem B 111:10109

    Article  CAS  Google Scholar 

  10. Bih L, Nadiri A, Aride J (2002) J Therm Anal Calorim 68:965

    Article  CAS  Google Scholar 

  11. Selvaraj U, Rao KJ (1988) J Non-Cryst Solids 104:300

    Article  CAS  Google Scholar 

  12. Koudelka L, Rösslerová I, Holubová J, Mošner P, Montagne L, Delevoye L (2011) J Non-Cryst Solids. doi:https://doi.org/10.1016/j.jnoncrysol.2011.03.006

    Article  CAS  Google Scholar 

  13. Yue Y-Z (2008) J Non-Cryst Solids 354:1112

    Article  CAS  Google Scholar 

  14. Bobovich YaS (1962) Opt Spektrosk 13:459

    CAS  Google Scholar 

  15. Chowdari BVR, Tan KL, Chia WT (1993) Mater Res Soc Symp Proc 293:325

    Article  CAS  Google Scholar 

  16. Šubčík J, Koudelka L, Mošner P, Montagne L, Trickot G, Delevoye L, Gregora I (2010) J Non-Cryst Solids 356:2509

    Article  Google Scholar 

  17. Masse R, Averbuch-Pouchot MT, Durif A (1985) J Solid State Chem 58:157

    Article  CAS  Google Scholar 

  18. Kissinger HE (1957) Anal Chem 29:1702

    Article  CAS  Google Scholar 

  19. Šesták J, Berggren G (1971) Thermochim Acta 3:1

    Article  Google Scholar 

  20. Isaac M, Jayasree V, Suresh G, Nayar VU (1992) Ind J Phys B 66:65

    Google Scholar 

  21. Flower GL, Baskaran GS, Reddy MS, Veeraiah N (2007) Phys B 2393:61

    Article  Google Scholar 

  22. Morgan SH, Magruder RH (1990) J Am Ceram Soc 73:753

    Article  CAS  Google Scholar 

  23. Kierkegaard P (1961) Ark Kemi 18:521

    Google Scholar 

  24. Joint Committee on Powder Diffraction Standards, International Centre of Diffraction Data, Swarthmore, PA, USA

Download references

Acknowledgements

The authors are grateful for the financial support from the research project No. P106/10/0283 of the Grant Agency of Czech Republic and from the research project No. 0021627501 of the Ministry of Education of Czech Republic.

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Authors and Affiliations

  1. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, 532 10, Pardubice, Czech Republic

    Ivana Rösslerová, Ladislav Koudelka, Zdeněk Černošek & Petr Mošner

  2. Joint Laboratory of Solid State Chemistry of Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic and the University of Pardubice, 532 10, Pardubice, Czech Republic

    Ludvík Beneš

Authors
  1. Ivana Rösslerová
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  2. Ladislav Koudelka
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  3. Zdeněk Černošek
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  4. Petr Mošner
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  5. Ludvík Beneš
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Correspondence to Ladislav Koudelka.

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Rösslerová, I., Koudelka, L., Černošek, Z. et al. Thermal properties and crystallization of PbO–MoO3–P2O5 glasses. J Mater Sci 46, 6751–6757 (2011). https://doi.org/10.1007/s10853-011-5631-4

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