Abstract
This paper reports a comparative study on structure-property relationship of acrylic rubber (ACM)/silica, epoxidised natural rubber (ENR)/silica and poly (vinyl alcohol) (PVA)/silica hybrid nanocomposites prepared by sol-gel technique under different pH levels (pH = 1.0–13.0), probably for the first time. The initial concentration of tetraethoxysilane (TEOS) (used as the precursor for silica) was kept at 45 wt%, and tetrahydrofuran (THF) for ACM/silica and ENR/silica while water for PVA/silica were taken as solvents. TEOS to water mole ratio was maintained at 1:2 for the rubber/silica systems to accomplish the sol-gel reaction. The structure of the resultant hybrid composites was determined by using electron microscopy, Fourier Transform infrared spectroscopy and solubility. Dynamic mechanical and mechanical properties were also investigated. The silica particles were found to exist as nanoparticles (average diameter <100 nm) at low pH (≤ 2.0) beyond which these aggregate, although the amount of silica generation was not strictly influenced by the various pH conditions in all the systems. These nanocomposites were optically clear and showed superior mechanical reinforcement over the micro-composites containing aggregated silica structures with lower optical clarity. The nanocomposites exhibited higher storage modulus both at the glassy and the rubbery regions as compared to those micro-composites. The loss tangent peak heights were also minimum and the Tg shifted to higher temperature for those nanocomposites. The maximum improvement of mechanical properties was observed with the PVA/silica nanocomposites due to higher level of interaction between the hydroxyl groups of PVA and the silanol groups of the silica phase.
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References
Foussaier O, Menetrier M, Videau J-J, Duguet E (2000) Mater Lett 42:305
Hu ZM, Slaterbeck AF, Selisker CJ, Ridgway TH, Heinman WR (1999) Langmuir 15:767
Grady BP, Start PR, Mauritz KA (2001) J Polym Sci Part B: Polym Phys 39:197
Tang M-Y, Mark JE (1984) Macromolecules 17:2613
Jitianu A, Gartner M, Zaharescu M, Cristea D, Manea E (2003) Mat Sci Eng C23:301
Chan C-K, Peng S-L, Chu I-M, Ni S-C (2001) Polymer 42:4189
Chan C-K, Chu I-M (2001) Polymer 42:6823
Landry CJT, Coltrain BK, Brady BK (1992) Polymer 33:1486
Huang H-H, Orler B, Wilkis GL (1987) Macromolecules 20:1322
Zerda TW, Artaki I, Jonas J (1986) J Non Cryst Solids 81:365
Himmel B, Gerber T, Burger H (1987) J Non Cryst Solids 91:1322
Bandyopadhyay A, Bhowmick AK, De Sarkar M (2004) J Appl Polym Sci 93:2579
Bandyopadhyay A, De Sarkar M, Bhowmick AK (2004) Rubber Chem Technol 77:830
Bandyopadhyay A, De Sarkar M, Bhowmick AK (2005) J Mater Sci 40:5233
Bandyopadhyay A, De Sarkar M, Bhowmick AK (2005) J Appl Polym Sci 95:1418
Bandyopadhyay A, De Sarkar M, Bhowmick AK (2005) J Mater Sci 40:52
Socrates G (1980) In: IR characteristic group frequencies, Wiley, New York
Nishino H, Takahashi R, Sato S, Sodesawa T (2004) J Non Cryst Solids 333:284
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Bandyopadhyay, A., De Sarkar, M. & Bhowmick, A.K. Structure-property relationship in sol-gel derived polymer/silica hybrid nanocomposites prepared at various pH. J Mater Sci 41, 5981–5993 (2006). https://doi.org/10.1007/s10853-006-0254-x
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DOI: https://doi.org/10.1007/s10853-006-0254-x