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High Selectivity of Cyclohexane Dehydrogenation for H2 Evolution Over Cu/SBA-15 Catalyst

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Abstract

The effects of metal particle size on catalytic activities of Cu/SBA-15 with different Cu content were investigated for high selectivity of cyclohexane dehydrogenation. Overall, the smaller Cu nanoparticles exhibit higher hydrogen evolution rate or lower active energy barrier. But, even when the smaller CuO nanoparticles have formed on the catalyst with lower Cu content during the calcination, they would be more prone to sinter after reduction. An appropriate Cu content could lead to form amounts of stable and small Cu nanoparticles after high-temperature treatment with the space limitation by ordered channels of SBA-15.

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Authors and Affiliations

  1. Institute of Catalytic Reaction Engineering, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310014, People’s Republic of China

    Zhijun **a, Huayan Liu, Hanfeng Lu, Zekai Zhang & Yinfei Chen

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  1. Zhijun **a
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  2. Huayan Liu
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  3. Hanfeng Lu
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  4. Zekai Zhang
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  5. Yinfei Chen
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Correspondence to Yinfei Chen.

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**a, Z., Liu, H., Lu, H. et al. High Selectivity of Cyclohexane Dehydrogenation for H2 Evolution Over Cu/SBA-15 Catalyst. Catal Lett 147, 1295–1302 (2017). https://doi.org/10.1007/s10562-017-2033-5

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  • DOI: https://doi.org/10.1007/s10562-017-2033-5

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